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Consider the reaction: C(2)H(5)O^(-)+ Di...

Consider the reaction: `C_(2)H_(5)O^(-)`+ Dimethyl sulphate `(Me-O-overset(O)overset(||)underset(O)underset(||)S-O-Me)rarr`
The leaving group is:

A

`MeOSO_(2)O^(-)`

B

`MeO^(-)`

C

`Me(-)`

D

`MeOSO_(2)^(-)`

Text Solution

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The correct Answer is:
To determine the leaving group in the reaction between ethoxide ion (C₂H₅O⁻) and dimethyl sulfate (Me₂SO₄), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the reaction are the ethoxide ion (C₂H₅O⁻) and dimethyl sulfate (Me₂SO₄). 2. **Understand the Structure of Dimethyl Sulfate**: Dimethyl sulfate can be represented as: \[ \text{Me-O-S(=O)(=O)-O-Me} \] Here, the sulfur atom is bonded to two methyl groups and has a sulfonate structure. 3. **Recognize the Nucleophile**: The ethoxide ion (C₂H₅O⁻) acts as a nucleophile. It has a negative charge and is capable of attacking electrophilic centers. 4. **Mechanism of Reaction**: When the ethoxide ion attacks one of the methyl groups in dimethyl sulfate, the electrons from the C-O bond will move towards the oxygen, creating a negative charge on the oxygen and causing the methyl group to become a good leaving group. 5. **Identify the Leaving Group**: The leaving group in this reaction is the group that departs when the nucleophile attacks. In this case, the leaving group is: \[ \text{MeOSO}_2^- \] This group is formed when the ethoxide ion attacks the methyl group, resulting in the formation of ethyl methyl ether and the departure of the methyl sulfonate ion. 6. **Conclusion**: The leaving group in the reaction is: \[ \text{MeOSO}_2^- \] which corresponds to option A. ### Final Answer: The leaving group is: **MeOSO₂⁻** (option A). ---

To determine the leaving group in the reaction between ethoxide ion (C₂H₅O⁻) and dimethyl sulfate (Me₂SO₄), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants in the reaction are the ethoxide ion (C₂H₅O⁻) and dimethyl sulfate (Me₂SO₄). 2. **Understand the Structure of Dimethyl Sulfate**: ...
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