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The crown-guest complex is called an inc...

The crown-guest complex is called an inclusion compound. The crown ether allows the inorganic salt to dissolve in non-polar solvents. `KMnO_(4)` forms a complex with crown ether. In this complex, the host is…. and the guest is…… .

A

`K^(o+)` and crown ether

B

Crown ether and `K^(o+)`

C

`MnO_(4)^(-)` and crown ether

D

Crown ether and `MnO_(4)^(-)`

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To solve the question regarding the crown-guest complex formed by KMnO4 and crown ether, we need to identify the host and guest components of the complex. Here’s the step-by-step solution: ### Step 1: Understand the Components Crown ethers are cyclic compounds that contain multiple ether groups (-O-) in their structure. They can encapsulate cations (positively charged ions) due to the presence of electron-donating oxygen atoms. **Hint:** Recall the structure of crown ethers and their ability to interact with cations. ### Step 2: Identify the Complex Formation When KMnO4 (potassium permanganate) interacts with crown ether, the crown ether can solvate the potassium ion (K+). The oxygen atoms in the crown ether can coordinate with the potassium ion due to their electron-rich nature. **Hint:** Focus on the charge interactions; the crown ether's oxygen atoms are negatively charged and can attract the positively charged potassium ion. ### Step 3: Define Host and Guest In the context of supramolecular chemistry: - The **host** is the molecule that provides a cavity or environment for another molecule or ion to fit into. - The **guest** is the molecule or ion that is encapsulated or included within the host. In this case: - The **host** is the crown ether because it forms a cavity that can accommodate the guest. - The **guest** is the potassium ion (K+) from KMnO4, which is being encapsulated by the crown ether. **Hint:** Remember that the host is typically larger and provides a space for the smaller guest. ### Final Answer - **Host:** Crown ether - **Guest:** Potassium ion (K+) ### Summary In the complex formed by KMnO4 and crown ether, the crown ether acts as the host, while the potassium ion (K+) serves as the guest. This interaction allows the inorganic salt to dissolve in non-polar solvents, demonstrating the unique properties of crown ethers in supramolecular chemistry.

To solve the question regarding the crown-guest complex formed by KMnO4 and crown ether, we need to identify the host and guest components of the complex. Here’s the step-by-step solution: ### Step 1: Understand the Components Crown ethers are cyclic compounds that contain multiple ether groups (-O-) in their structure. They can encapsulate cations (positively charged ions) due to the presence of electron-donating oxygen atoms. **Hint:** Recall the structure of crown ethers and their ability to interact with cations. ### Step 2: Identify the Complex Formation ...
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CENGAGE CHEMISTRY ENGLISH-ALCOHOL,PHENOL AND ETHERS-Exercises Single Correct
  1. In Zeisel's method for the detrmination of methoxyl groups, a sample o...

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  2. The crown ethers are heterocyclic polyethers, usually with at least fo...

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  3. The crown-guest complex is called an inclusion compound. The crown eth...

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  4. Which of the following is not used as inhalation ananesthetic ?

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  5. Which of the following is not used as flavouring agent in perfumes ?

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  6. The presence of peroxides in old samples of ethers is detected by shak...

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  7. Which of the following is oxetane?

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  8. Which of the following ether is called phenetole?

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  9. Which of the following structure represents Vanillin ?

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  10. Which of the following ethers is presents in clove oil ?

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  11. The products (A) and (B) are:

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  12. The products (A) and (B) are:

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  13. The products (A) and (B) are:

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  14. CH(3)-CH(2)-O-CH(2)-CH(3)+O(2)overset(hv)rarr (A) The product (A) is:

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  15. Which of the following reactions is possible ?

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  16. Which of the following reactions is possible ?

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  17. Give the decreasing order of reactivity of the following alkyl halides...

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  18. HO-CH(2)-CH(2)-CH(2)-CH(2)CI overset(O^(-)H)rarr (A) Which of the foll...

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  19. CH(3)OH+C(2)H(5)OH overset(H^(o+))rarr Products

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  20. The products (x) and (y) are:

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