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The decreasing order of ease of hydrolys...

The decreasing order of ease of hydrolysis of the following esters is :
(I) `MeCOOPh`
(II)
(III)
(IV) .

A

`(II) gt (I) gt (IV) gt (III)`

B

`(I) gt (II) gt (III) gt (IV)`

C

`(III) gt (IV) gt (I) gt (II)`

D

`(IV) gt (III) gt (II) gt (I)`

Text Solution

Verified by Experts

The correct Answer is:
A

More `EWG` favours acyl substitution or hydrolysis of acid derivative.
`II [(-NO_2),(-I)`, and `(-R)], gt (I) [(Ph),(-I)`, and` (+R), ("Standard")] gt (IV) [Me,(+I)` and `H.C.]gt (III) [("Ome"(-I)` and `(-R)`, net more `EDG` than (IV)].
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CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. Product ( C) is :

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  2. Give two examples of reactions which are driven by enthalpy change.

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  3. The decreasing order of ease of hydrolysis of the following esters is ...

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  4. The boiling points of ethyl acetate and CH3 OH, respectively, are 77^@...

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  5. Carboxylic acid, although unreactive to alcohols, reacts in the presen...

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  6. The major product ( C) in the reaction is : .

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  7. Which of the following is the best method for the synthesis of ester (...

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  8. Which of the following is the best method for the synthesis of alpha-h...

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  9. Which of the following statements is wrong about the transesterificati...

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  10. The molecular weight of benzoic acid in benzene as determined by depre...

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  11. Which of the following reaction is expected to readily give a hydrocar...

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  12. Which of the following reactions is not possible ?

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  13. underset((A)) (PhCONH2) underset(KOBr)rarr (B) underset(MeOH)rarr (C) ...

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  14. It has been found that 221.4J is needed to heat 30g of ethanol from 15...

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  15. underset((A))(PhCOOH)underset(underset((ii)Ag(2)O //Pt//MeOH)((ii)CH(2...

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  16. Calculate energy of 2mole of photons of radiation whose frequency is 5...

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  17. underset((A)) (EtCOOMe) overset("(i)" NH2 NH2 "(ii)" HNO2) underset("(...

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  18. underset((A))("PhCOOMe") overset("(i)" NH2 OH) underset("(ii)" overset...

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  19. Product (B) is :

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  20. Which of the following tests would help in the distinction of HCOOH an...

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