Home
Class 12
CHEMISTRY
underset((A))(PhCOOH)underset(underset((...

`underset((A))(PhCOOH)underset(underset((ii)Ag_(2)O //Pt//MeOH)((ii)CH_(2)N_(2)))overset((i)SOCI_(2))rarr (B)`
Product `(B)` is :

A

`PhCONH_2`

B

`PhCH_2 COOH`

C

`PhCH_2 COOMe`

D

`PhCONHMe`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions involving benzoic acid (PhCOOH) and the reagents mentioned. ### Step 1: Reaction of Benzoic Acid with SOCl2 - **Starting Material**: Benzoic acid (PhCOOH) - **Reagent**: Thionyl chloride (SOCl2) - **Reaction**: When benzoic acid reacts with SOCl2, it converts the carboxylic acid (-COOH) group into an acyl chloride (RCOCl). **Product**: PhC(=O)Cl (Benzoyl chloride) ### Step 2: Reaction of Benzoyl Chloride with CH2N2 - **Starting Material**: Benzoyl chloride (PhC(=O)Cl) - **Reagent**: Diazomethane (CH2N2) - **Reaction**: Diazomethane reacts with benzoyl chloride to form a methyl ester. The reaction involves the nucleophilic attack of the diazomethane on the carbonyl carbon of the acyl chloride, leading to the formation of a methyl ester. **Product**: PhC(=O)OCH3 (Methyl benzoate) ### Step 3: Reaction of Methyl Benzoate with Ag2O, Pt, and MeOH - **Starting Material**: Methyl benzoate (PhC(=O)OCH3) - **Reagents**: Silver oxide (Ag2O), Platinum (Pt), and Methanol (MeOH) - **Reaction**: In the presence of Ag2O and Pt, the methyl ester undergoes a rearrangement and reduction process. The silver oxide acts as an oxidizing agent, and the platinum serves as a catalyst. This leads to the formation of a more stable product through rearrangement. **Product**: The final product after rearrangement and reduction is likely to be a substituted compound, specifically an ester. ### Final Product (B) After going through these steps, the final product (B) can be identified as: - **Product (B)**: CH2COOMe (Methyl ester of a carboxylic acid) ### Summary The final product (B) is methyl ester of a carboxylic acid, which can be represented as CH2COOMe. ---

To solve the problem step by step, we will analyze the reactions involving benzoic acid (PhCOOH) and the reagents mentioned. ### Step 1: Reaction of Benzoic Acid with SOCl2 - **Starting Material**: Benzoic acid (PhCOOH) - **Reagent**: Thionyl chloride (SOCl2) - **Reaction**: When benzoic acid reacts with SOCl2, it converts the carboxylic acid (-COOH) group into an acyl chloride (RCOCl). **Product**: PhC(=O)Cl (Benzoyl chloride) ...
Promotional Banner

Topper's Solved these Questions

  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Assertion-Reasoning)|10 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Single Correct)|10 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Multiple Correct)|34 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|23 Videos

Similar Questions

Explore conceptually related problems

underset((A))(MeCH_(2)COOH)underset(underset((iii)Ag_(2)O //Pt)((ii)CH_(2)N_(2)))overset((i)SOCI)rarr(B)overset(H_(2)O)rarr(C) Which of the following statements are correct about the given reaction.

In the given reaction CH_(3)-COOH underset(underset("(iii) "H_(2)O //H^(o+))("(ii) "NaCN))overset("(i) Red "-P+Br_(2))rarr(X) 'X' will be

Identify (A) in the following reaction sequence underset("iodoform test")underset("Gives Positive")(A)underset(underset("(iii) Conc. "H_(2)SO_(4)//Delta)("(ii) "H^(+),H_(2)O))overset("(i) "CH_(3)MgBr)rarr(B)overset(O_(y)//Zn,H_(2)O)rarr

MeCOOEt underset(underset((iii)^(Theta)OH)((ii)HNO_(2)))overset((i)NH_(2)NH_(2))rarr (B)underset(MeOH)rarr(C) Which of the following statements are correct about the given reaction?

underset((A))("PhCOOMe") overset("(i)" NH_2 OH) underset("(ii)" overset (Ө)O H "(iii)" EtOH)rarr (B) Product (B) is :

Ph-underset(underset(Cl)(|))(CH)-CH_(2)-Cl underset(underset(("iii") H^(+))(("ii")NaNH_(2)))overset(("i")Alc.kOH)(rarr) A overset("Cold alk." KMnO_(4))(rarr)B underset("warm")overset("NaOH")(rarr)C The product 'C' eill be

underset((A))(MeCH)=O+underset((B))(H_(2)NOH) overset(HCOONa)underset(Delta)rarr (C )+H_(2)O Product (C ) is:

CH_(2) = CH_(2) + B_(2) H_(6) underset(H_(2)O_(2))overset(NaOH) to Product is :

CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. underset((A)) (PhCONH2) underset(KOBr)rarr (B) underset(MeOH)rarr (C) ...

    Text Solution

    |

  2. It has been found that 221.4J is needed to heat 30g of ethanol from 15...

    Text Solution

    |

  3. underset((A))(PhCOOH)underset(underset((ii)Ag(2)O //Pt//MeOH)((ii)CH(2...

    Text Solution

    |

  4. Calculate energy of 2mole of photons of radiation whose frequency is 5...

    Text Solution

    |

  5. underset((A)) (EtCOOMe) overset("(i)" NH2 NH2 "(ii)" HNO2) underset("(...

    Text Solution

    |

  6. underset((A))("PhCOOMe") overset("(i)" NH2 OH) underset("(ii)" overset...

    Text Solution

    |

  7. Product (B) is :

    Text Solution

    |

  8. Which of the following tests would help in the distinction of HCOOH an...

    Text Solution

    |

  9. Which of the following does not contain (-COOH) group ?

    Text Solution

    |

  10. Acids do not give the characteristic reaction of (C=O) group because o...

    Text Solution

    |

  11. The addition of Hbr to CH2 = CHCOOH results in the formation of.

    Text Solution

    |

  12. Mark the correct order of increasing reactivity.

    Text Solution

    |

  13. CH3COOH overset(Br2//P) rarr (Y) overset((i) KCN) underset((ii) H3 O^...

    Text Solution

    |

  14. Find out atomic number, mass number, number of electron and neutron in...

    Text Solution

    |

  15. Electrolytic reduction of oxalic acid produces :

    Text Solution

    |

  16. When glycolic acid is subjected to reduction with HI, the product form...

    Text Solution

    |

  17. When lactic acid is subjected to oxidation with Fenton's reagent, the ...

    Text Solution

    |

  18. How will you convert ethyne to benzene?

    Text Solution

    |

  19. Treatment of tartaric acid with Fenton's reagent gives :

    Text Solution

    |

  20. A hydrocarbon C6 H12 decolourises bromine solution and yields n-hexane...

    Text Solution

    |