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underset((A))("PhCOOMe") overset("(i)" N...

`underset((A))("PhCOOMe") overset("(i)" NH_2 OH) underset("(ii)" overset (Ө)O H "(iii)" EtOH)rarr (B)`
Product `(B)` is :

A

`PhNH_2`

B

`MeNH_2`

C

`PhNHCOOEt`

D

`PhNHCOOMe`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reaction of the compound PhCOOMe (product A) with the reagents provided in the question. ### Step 1: Identify Product A Product A is PhCOOMe, which is methyl benzoate. The structure can be represented as: - Ph: Phenyl group (C6H5) - COOMe: Methyl ester group (COOCH3) ### Step 2: Reaction with NH2OH The first reagent is hydroxylamine (NH2OH). When methyl benzoate reacts with hydroxylamine, it forms an oxime. The reaction can be represented as follows: - Methyl benzoate + NH2OH → Benzamide oxime (PhC(=NOH)OCH3) + Methanol (MeOH) ### Step 3: Reaction with OH⁻ The next step involves the reaction of the oxime with hydroxide ion (OH⁻). This step leads to the elimination of a water molecule and forms a nitrile: - Benzamide oxime + OH⁻ → PhC(=N)O + H2O ### Step 4: Rearrangement The product from the previous step undergoes a rearrangement (likely a Beckmann rearrangement), which converts the oxime into an amide: - PhC(=N)O → PhC(=O)NH2 ### Step 5: Reaction with Ethanol (EtOH) Finally, the amide reacts with ethanol. This reaction typically results in the formation of an ethyl carbamate: - PhC(=O)NH2 + EtOH → PhC(=O)OEt + NH3 ### Final Product B The final product (B) is therefore: - PhC(=O)OEt (Ethyl benzoate) ### Summary of Product B Product B is PhNHCOOEt, which can be written as: - Ethyl benzoate (PhC(=O)OEt) ### Final Answer Thus, the final product (B) is PhNHCOOEt. ---

To solve the problem step by step, we will analyze the reaction of the compound PhCOOMe (product A) with the reagents provided in the question. ### Step 1: Identify Product A Product A is PhCOOMe, which is methyl benzoate. The structure can be represented as: - Ph: Phenyl group (C6H5) - COOMe: Methyl ester group (COOCH3) ### Step 2: Reaction with NH2OH ...
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