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Acids do not give the characteristic rea...

Acids do not give the characteristic reaction of `(C=O)` group because of :

A

Dimerisation

B

Resonance

C

Cyclic structures

D

Attached alkyl radical

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The correct Answer is:
To solve the question "Acids do not give the characteristic reaction of (C=O) group because of:", we need to analyze the structure and behavior of carboxylic acids compared to aldehydes and ketones. ### Step-by-Step Solution: 1. **Understanding the Structure of Carboxylic Acids**: - Carboxylic acids have a functional group represented as -COOH. This group contains a carbonyl (C=O) and a hydroxyl (O-H) group. - The carbonyl carbon is bonded to both an oxygen atom (in the carbonyl) and a hydroxyl group. 2. **Resonance in Carboxylic Acids**: - In carboxylic acids, the lone pair of electrons on the oxygen atom of the hydroxyl group can participate in resonance with the carbonyl group. - This results in the delocalization of electrons, leading to the formation of resonance structures. 3. **Effect of Resonance on Reactivity**: - Due to resonance, the C=O bond in carboxylic acids does not behave like a typical carbonyl bond found in aldehydes and ketones. - The resonance stabilizes the structure, which means that the pi electrons of the C=O bond are delocalized and do not participate in reactions as freely as they would in aldehydes and ketones. 4. **Comparison with Aldehydes and Ketones**: - Aldehydes and ketones do not have such resonance stabilization; their C=O bonds are more reactive and can participate in characteristic reactions. - Therefore, the presence of resonance in carboxylic acids inhibits them from undergoing the same reactions as aldehydes and ketones. 5. **Conclusion**: - The characteristic reactions of the C=O group are not exhibited by carboxylic acids due to the resonance effect, which delocalizes the pi electrons of the C=O bond. ### Final Answer: The correct answer to the question is **resonance**. ---

To solve the question "Acids do not give the characteristic reaction of (C=O) group because of:", we need to analyze the structure and behavior of carboxylic acids compared to aldehydes and ketones. ### Step-by-Step Solution: 1. **Understanding the Structure of Carboxylic Acids**: - Carboxylic acids have a functional group represented as -COOH. This group contains a carbonyl (C=O) and a hydroxyl (O-H) group. - The carbonyl carbon is bonded to both an oxygen atom (in the carbonyl) and a hydroxyl group. ...
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CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. Which of the following tests would help in the distinction of HCOOH an...

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  2. Which of the following does not contain (-COOH) group ?

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  3. Acids do not give the characteristic reaction of (C=O) group because o...

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  4. The addition of Hbr to CH2 = CHCOOH results in the formation of.

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  5. Mark the correct order of increasing reactivity.

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  6. CH3COOH overset(Br2//P) rarr (Y) overset((i) KCN) underset((ii) H3 O^...

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  7. Find out atomic number, mass number, number of electron and neutron in...

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  8. Electrolytic reduction of oxalic acid produces :

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  9. When glycolic acid is subjected to reduction with HI, the product form...

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  10. When lactic acid is subjected to oxidation with Fenton's reagent, the ...

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  11. How will you convert ethyne to benzene?

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  12. Treatment of tartaric acid with Fenton's reagent gives :

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  13. A hydrocarbon C6 H12 decolourises bromine solution and yields n-hexane...

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  14. An organic liquid of the composition C4 H8 O2 yields a sodium salt of ...

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  15. On heating calcium acetate and calcium formate, the product formed is ...

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  16. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  17. One mole of an organic compound is found to require only 0.5 mol of ox...

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  18. Identify Z in the following series CH(2)=CH(2) overset(HBr)rarr X ov...

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  19. Which one of the following has the maximum acid strength ?

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  20. Formic acid is obtained when

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