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The addition of Hbr to CH2 = CHCOOH resu...

The addition of `Hbr` to `CH_2 = CHCOOH` results in the formation of.

A

`alpha-`Bromopropanoic acid

B

`beta-`Bromopropanoic acid as the major product

C

None of the above

D

Both (a) and (b) in equal proportion.

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To solve the problem of what compound is formed when HBr is added to CH₂=CHCOOH (acrylic acid), we can follow these steps: ### Step 1: Identify the Reactants The reactant is acrylic acid, which has the structure CH₂=CHCOOH. It contains a double bond (C=C) and a carboxylic acid group (COOH). ### Step 2: Understand the Reaction Mechanism When HBr is added to an alkene, the reaction typically follows Markovnikov's rule. This means that the hydrogen (H) from HBr will attach to the carbon with the most hydrogen atoms already attached, while the bromine (Br) will attach to the carbon with fewer hydrogen atoms. ### Step 3: Formation of Carbocation In this case, the double bond between the two carbon atoms will break. The addition of HBr leads to the formation of a carbocation. The H+ ion will add to the terminal carbon (the one with two hydrogens), resulting in a more stable secondary carbocation at the other carbon. ### Step 4: Nucleophilic Attack by Bromide Ion Once the carbocation is formed, the Br- ion (which is negatively charged) will attack the positively charged carbon atom. This will lead to the formation of a new bond between the carbon and bromine. ### Step 5: Final Product Formation The final product will be a bromo acid. The structure of the product can be represented as CH₂Br-CH₂-COOH. This compound is known as beta-bromo propanoic acid, as the bromine is attached to the beta carbon relative to the carboxylic acid group. ### Conclusion The addition of HBr to CH₂=CHCOOH results in the formation of beta-bromo propanoic acid. ### Final Answer The compound formed is **beta-bromo propanoic acid (CH₂Br-CH₂-COOH)**. ---

To solve the problem of what compound is formed when HBr is added to CH₂=CHCOOH (acrylic acid), we can follow these steps: ### Step 1: Identify the Reactants The reactant is acrylic acid, which has the structure CH₂=CHCOOH. It contains a double bond (C=C) and a carboxylic acid group (COOH). ### Step 2: Understand the Reaction Mechanism When HBr is added to an alkene, the reaction typically follows Markovnikov's rule. This means that the hydrogen (H) from HBr will attach to the carbon with the most hydrogen atoms already attached, while the bromine (Br) will attach to the carbon with fewer hydrogen atoms. ...
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CENGAGE CHEMISTRY ENGLISH-CARBOXYLIC ACIDS AND THEIR DERIVATIVES-Exercises (Singlecorrect)
  1. Which of the following does not contain (-COOH) group ?

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  2. Acids do not give the characteristic reaction of (C=O) group because o...

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  3. The addition of Hbr to CH2 = CHCOOH results in the formation of.

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  4. Mark the correct order of increasing reactivity.

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  5. CH3COOH overset(Br2//P) rarr (Y) overset((i) KCN) underset((ii) H3 O^...

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  6. Find out atomic number, mass number, number of electron and neutron in...

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  7. Electrolytic reduction of oxalic acid produces :

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  8. When glycolic acid is subjected to reduction with HI, the product form...

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  9. When lactic acid is subjected to oxidation with Fenton's reagent, the ...

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  10. How will you convert ethyne to benzene?

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  11. Treatment of tartaric acid with Fenton's reagent gives :

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  12. A hydrocarbon C6 H12 decolourises bromine solution and yields n-hexane...

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  13. An organic liquid of the composition C4 H8 O2 yields a sodium salt of ...

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  14. On heating calcium acetate and calcium formate, the product formed is ...

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  15. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  16. One mole of an organic compound is found to require only 0.5 mol of ox...

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  17. Identify Z in the following series CH(2)=CH(2) overset(HBr)rarr X ov...

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  18. Which one of the following has the maximum acid strength ?

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  19. Formic acid is obtained when

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  20. The reaction of HCOOH with conc. H2 SO4 gives :

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