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CH3COOH overset(Br2//P) rarr (Y) overse...

`CH_3COOH overset(Br_2//P) rarr (Y) overset((i) KCN) underset((ii) H_3 O^+)rarr (X)`
Here, `(X)` is :

A

Glycollic acid

B

`alpha`-Hydroxypropionic acid

C

Succinic acid

D

Malonic acid

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AI Generated Solution

The correct Answer is:
To solve the question step by step, we will analyze the reactions involving acetic acid (CH₃COOH) and the reagents provided. ### Step 1: Reaction of Acetic Acid with Bromine and Phosphorus 1. **Starting Material**: Acetic acid (CH₃COOH). 2. **Reagents**: Bromine (Br₂) and Phosphorus (P). 3. **Reaction Type**: This is a halogenation reaction where acetic acid undergoes bromination. 4. **Product Formation**: The bromination occurs at the alpha position (the carbon adjacent to the carboxylic acid group), resulting in the formation of 2-bromopropanoic acid (BrCH₂COOH). **Product (Y)**: BrCH₂COOH ### Step 2: Reaction of Product Y with KCN 1. **Starting Material**: 2-bromopropanoic acid (BrCH₂COOH). 2. **Reagents**: Potassium cyanide (KCN) in alcoholic solution. 3. **Reaction Type**: Nucleophilic substitution reaction (S_N2) occurs here, where the cyanide ion (CN⁻) acts as a nucleophile and replaces the bromine atom. 4. **Product Formation**: The product formed is 2-cyanoacetic acid (CNCH₂COOH). **Intermediate Product**: CNCH₂COOH ### Step 3: Hydrolysis of the Intermediate Product 1. **Starting Material**: 2-cyanoacetic acid (CNCH₂COOH). 2. **Reagents**: Acidic hydrolysis using H₃O⁺ (hydronium ion). 3. **Reaction Type**: The cyano group (CN) undergoes hydrolysis to form a carboxylic acid. 4. **Product Formation**: The hydrolysis of the cyano group leads to the formation of malonic acid (HOOC-CH₂-COOH). **Final Product (X)**: Malonic acid (HOOC-CH₂-COOH) ### Conclusion The final product (X) after the complete reaction sequence is malonic acid. **Answer**: (X) is malonic acid. ---

To solve the question step by step, we will analyze the reactions involving acetic acid (CH₃COOH) and the reagents provided. ### Step 1: Reaction of Acetic Acid with Bromine and Phosphorus 1. **Starting Material**: Acetic acid (CH₃COOH). 2. **Reagents**: Bromine (Br₂) and Phosphorus (P). 3. **Reaction Type**: This is a halogenation reaction where acetic acid undergoes bromination. 4. **Product Formation**: The bromination occurs at the alpha position (the carbon adjacent to the carboxylic acid group), resulting in the formation of 2-bromopropanoic acid (BrCH₂COOH). ...
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  9. Treatment of tartaric acid with Fenton's reagent gives :

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  13. CH3 CH=CHCHO is oxidised to CH3 CH=CHCOOH using :

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  15. Identify Z in the following series CH(2)=CH(2) overset(HBr)rarr X ov...

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  16. Which one of the following has the maximum acid strength ?

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  18. The reaction of HCOOH with conc. H2 SO4 gives :

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  19. The compound which react with Fehling solution is :

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