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Name the reaction sequence. RCOOH over...

Name the reaction sequence.
`RCOOH overset(SOCl_2)rarr RCOCl overset(CH_2N_2)rarr RCOCHN_2 overset (H_2O) underset(Ag)rarr RCH_2 COOH`.

A

Arndt-Eistert synthesis

B

Wolff's reaction

C

Reppe's process

D

Wacker's process

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will analyze the given reaction sequence step by step: 1. **Starting Material: Carboxylic Acid (RCOOH)** - The reaction begins with a carboxylic acid, RCOOH. 2. **First Reaction: Conversion to Acyl Chloride** - The carboxylic acid reacts with thionyl chloride (SOCl2). - This reaction converts the carboxylic acid into an acyl chloride (RCOCl) by replacing the hydroxyl group (-OH) with a chlorine atom (-Cl). - **Reaction:** RCOOH + SOCl2 → RCOCl + SO2 + HCl 3. **Second Reaction: Formation of Diazoketone** - The acyl chloride (RCOCl) then reacts with diazomethane (CH2N2). - In this reaction, the chlorine atom is replaced by a diazomethyl group (CH2N2), resulting in the formation of a diazoketone (RCOCHN2). - **Reaction:** RCOCl + CH2N2 → RCOCHN2 + N2 + HCl 4. **Third Reaction: Hydrolysis in the Presence of Silver** - The diazoketone (RCOCHN2) undergoes hydrolysis in the presence of water (H2O) and silver (Ag). - This step leads to the formation of a carboxylic acid with an additional carbon atom (RCH2COOH), effectively extending the carbon chain. - **Reaction:** RCOCHN2 + H2O + Ag → RCH2COOH + N2 + Ag 5. **Final Product: Homologous Carboxylic Acid** - The final product of this reaction sequence is RCH2COOH, which is a homolog of the original carboxylic acid (RCOOH). ### Summary of the Reaction Sequence - The entire reaction sequence can be summarized as: - RCOOH (carboxylic acid) → RCOCl (acyl chloride) → RCOCHN2 (diazoketone) → RCH2COOH (homologous carboxylic acid) ### Name of the Reaction Sequence - This reaction sequence is known as **"Arndt-Eistert synthesis."** It is a method for converting a carboxylic acid into its homologous carboxylic acid.

To solve the problem, we will analyze the given reaction sequence step by step: 1. **Starting Material: Carboxylic Acid (RCOOH)** - The reaction begins with a carboxylic acid, RCOOH. 2. **First Reaction: Conversion to Acyl Chloride** - The carboxylic acid reacts with thionyl chloride (SOCl2). - This reaction converts the carboxylic acid into an acyl chloride (RCOCl) by replacing the hydroxyl group (-OH) with a chlorine atom (-Cl). ...
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