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Give the reactants of the following amin...

Give the reactants of the following amines obtained by reduction with ` LAH`.
`

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` (##KSV_CHM_ORG_P2_C15_E01_001_S01.png" width="80%">
`R rArr CH_(3)-overset(CH_(3))overset(|)(CH)-`
d. Let the ketone be :
`R_(1)-overset(O)overset(||)(C)-R_(2)overset(CH_(3)MgBr)underset(H_(3)O^(o+))rarr R_(2)-overset(OH)overset(|)underset(CH_(3))underset(|)(C)-R_(2)`
`rArr CH_(3)-overset(CH_(3))overset(|)underset(OH)underset(|)(C)-C_(2)H_(5) R_(1) rArr CH_(3-), R_(2) rArr C_(2)H_(5-)`,
` (##KSV_CHM_ORG_P2_C15_E01_001_S02.png" width="80%">
`(C) rArr CH_(3)-overset(C_(2)H_(5))overset(|)(C)=N.OH, (D) rArr CH_(3)-overset(C_(2)H_(5))overset(|)(CH)-NH_(2)`
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Knowledge Check

  • Which of the following can give 1° amine?

    A
    `Ph - overset(overset(CH_3)(|))CH - OH overset(NaCN, H^(oplus))(to)`
    B
    `Ph - CH = CH - overset(overset(O)(||))C - NH_(2) underset(CH_(3) OH) overset(NaOCI) (to)`
    C
    `Ph - C -= C -overset(overset(O)(||)) C - NH_(2) overset("NaOBr")( to)`
    D
    `Ph - overset(overset(O)(||))C - CI underset(Delta) overset(NaN_3) (to) , overset(LiAIH_4) (to)`

  • Which of the following give aniline by reduction of nitrobenzene?

    A
    `H_(2) // Pd- C`
    B
    `Sn + HCl`
    C
    `Fe+ HCl`
    D
    `LiAlH_(4)`

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