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Which of the following statements are c...

Which of the following statements are correct?

A

`CH_(3)overset(o+)(N) -= overset(Theta)(C)` on partial hydrolysis gives `N`-methyl methanamide.

B

`CH_(3)overset(o+)(N) -= overset(ɵ)(C)` on partial hydrolysis gives `CH_(3)NH_(2)` and `HCOOH`.

C

In an isocyanide, first an electrophile and then a nucleoplile add at the same `C` atom bearing negative charge.

D

In an isocyanide, first a nucleophile and then an electrophile add at the same `C` atom bearing negative charge.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements about the hydrolysis of isocyanides are correct, we will analyze the process of hydrolysis step by step. ### Step 1: Understanding Isocyanides Isocyanides have the general structure R-N≡C, where R is an alkyl group. In this case, we have CH3-N≡C, where the nitrogen is positively charged and the carbon is negatively charged. **Hint:** Recall the structure of isocyanides and their charge distribution. ### Step 2: Partial Hydrolysis of Isocyanides In partial hydrolysis, an electrophile (H⁺) attacks the negatively charged carbon atom. This results in the formation of a bond between carbon and hydrogen, leading to a positively charged carbon and a nitrogen atom that now has a lone pair of electrons. **Hint:** Identify the role of electrophiles in chemical reactions. ### Step 3: Nucleophilic Attack Next, a nucleophile (OH⁻) attacks the positively charged carbon. This leads to the formation of a compound known as N-methylmethanamide (CH3NHC(=O)OH). **Hint:** Remember that nucleophiles are species that donate electron pairs. ### Step 4: Complete Hydrolysis In complete hydrolysis, water is added, and the bond between carbon and nitrogen breaks. This results in the formation of methanamine (CH3NH2) and formic acid (HCOOH). **Hint:** Differentiate between partial and complete hydrolysis based on the products formed. ### Step 5: Evaluating the Statements 1. **Statement A:** The partial hydrolysis of isocyanide gives N-methylmethanamide. **(Correct)** 2. **Statement B:** Partial hydrolysis gives ethanamide and formic acid. **(Incorrect, this is a product of complete hydrolysis)** 3. **Statement C:** In isocyanide, first an electrophile and then a nucleophile add to the same carbon atom bearing a negative charge. **(Correct)** 4. **Statement D:** In isocyanide, first a nucleophile and then an electrophile attack the same carbon atom bearing a negative charge. **(Incorrect)** ### Conclusion The correct statements are A and C. The incorrect statements are B and D. **Final Answer:** The correct statements are A and C.

To determine which statements about the hydrolysis of isocyanides are correct, we will analyze the process of hydrolysis step by step. ### Step 1: Understanding Isocyanides Isocyanides have the general structure R-N≡C, where R is an alkyl group. In this case, we have CH3-N≡C, where the nitrogen is positively charged and the carbon is negatively charged. **Hint:** Recall the structure of isocyanides and their charge distribution. ### Step 2: Partial Hydrolysis of Isocyanides ...
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