Home
Class 12
CHEMISTRY
The compound 1- (N-ethyl-N-methyl)- prop...

The compound 1- (N-ethyl-N-methyl)- propanamine forms non-superimposable mirror images . But this compound does not show optical activity because of the :

A

Absence fo a chiral (N) atom

B

Prersence of chiral (N) atom

C

Presence of lone pair on (N) atom

D

Rapid filipping of one form into the another

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the optical activity of the compound 1-(N-ethyl-N-methyl)-propanamine, we will analyze the structure and the concept of chirality in detail. ### Step-by-Step Solution: 1. **Identify the Structure**: - The compound 1-(N-ethyl-N-methyl)-propanamine consists of a propanamine backbone with an ethyl and a methyl group attached to the nitrogen atom. - The structure can be represented as follows: ``` CH3-CH2-N(CH3)-CH2-CH3 ``` 2. **Determine Chirality**: - A chiral center is typically a carbon atom bonded to four different substituents. However, in this case, the chiral center is the nitrogen atom. - The nitrogen atom has three different substituents: an ethyl group (C2H5), a methyl group (CH3), and a propyl group (C3H7) along with a lone pair of electrons. 3. **Mirror Image Formation**: - The compound can form non-superimposable mirror images due to the presence of the chiral nitrogen atom. This means that if you were to create a mirror image of the compound, it would not be possible to overlay the two structures perfectly. 4. **Optical Activity**: - Generally, compounds that have non-superimposable mirror images are optically active. However, in this case, the compound does not exhibit optical activity. - The reason for this is that the nitrogen atom can rapidly interconvert between its two configurations due to the presence of the lone pair of electrons. This rapid flipping or inversion prevents the compound from being stable in one specific chiral form. 5. **Conclusion**: - Although the compound has a chiral nitrogen atom, the rapid interconversion between its mirror images means that it does not maintain a stable chiral configuration. Therefore, it does not exhibit optical activity. ### Final Answer: The compound 1-(N-ethyl-N-methyl)-propanamine does not show optical activity despite forming non-superimposable mirror images because of the rapid flipping (inversion) of the nitrogen atom, which leads to interconversion between the two forms.

To solve the question regarding the optical activity of the compound 1-(N-ethyl-N-methyl)-propanamine, we will analyze the structure and the concept of chirality in detail. ### Step-by-Step Solution: 1. **Identify the Structure**: - The compound 1-(N-ethyl-N-methyl)-propanamine consists of a propanamine backbone with an ethyl and a methyl group attached to the nitrogen atom. - The structure can be represented as follows: ``` ...
Promotional Banner

Topper's Solved these Questions

  • ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion And Reasoning|9 Videos
  • ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct|10 Videos
  • ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Multiple Correct|18 Videos
  • NUCLEAR CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|13 Videos
  • P-BLOCK GROUP 15 ELEMENTS - THE NITROGEN FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Subjective)|28 Videos

Similar Questions

Explore conceptually related problems

Which one of the following compounds show optical activity

Which one of the following compounds show optical activity ?

Which of the following compounds can non-superimposable mirror images?

Which of the following compounds can have superimposable mirror image?

Which of the following is responsible for the inability of meso compound to show optical activity?

Presence of chiral center is not an essential condition to show optical isomerism. Essential condition is, compound should show non-superimposable mirror image. Allenes do not contain chiral center but show optical isomerism when different groups are attached on double bonded carbons. Biphenyls also show optical isomerism when both rings are perpendicular to each other and any ring should not contain plane of symmetry. Which of the following biphenyl compounds is optically active?

Presence of chiral center is not an essential condition to show optical isomerism. Essential condition is, compound should show non-superimposable mirror image. Allenes do not contain chiral center but show optical isomerism when different groups are attached on double bonded carbons. Biphenyls also show optical isomerism when both rings are perpendicular to each other and any ring should not contain plane of symmetry. Which of the following compounds can be resolved in enantiomeric form?

Presence of chiral center is not an essential condition to show optical isomerism. Essential condition is, compound should show non-superimposable mirror image. Allenes do not contain chiral center but show optical isomerism when different groups are attached on double bonded carbons. Biphenyls also show optical isomerism when both rings are perpendicular to each other and any ring should not contain plane of symmetry. Which of the following compounds is optically inactive?

Substance A is 1:1 mixture of two compounds I and II: Will the mixture show optical activity ?

Read the paragraph carefully and answer the questions given below it, Stereo//space isomerism in coordination compounds Gcometrical isomerism: Exhibited by square planer and octahedral complexes (not by tetrahedral complexes because relative positions are similar). If opposite positions have similar groups, it is trans, otherwise it is cis, Optical isomerism: Shown when mirror image is non-superimposable. Cis-isomer shows but trans isomer does not QHow many geometrical isomers are possible for the square planar complex [Pt(NO_(2))(Py)(NH_(3))(NH_(2)OH)]NO_(2)

CENGAGE CHEMISTRY ENGLISH-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP-Exercises Single Correct
  1. An orgnic compoud with the formula C3 H5 N hydrolysis forms a acid wh...

    Text Solution

    |

  2. In order to distinguigh between C2H5NH2 and C6H5NH2 which of the fol...

    Text Solution

    |

  3. The compound 1- (N-ethyl-N-methyl)- propanamine forms non-superimposab...

    Text Solution

    |

  4. Which of the following will yield phenlhydrazine hydrochloride ?

    Text Solution

    |

  5. An aromatic compounds 'X' with molecular formula C(8)H(10) produces on...

    Text Solution

    |

  6. CHCl3 overset (HNO3) (rarr) (X) In the above sequence , (X ) is :

    Text Solution

    |

  7. Which of the following is formed when RNH2 reacts with RCHO?

    Text Solution

    |

  8. Which of the following represents the poinsonous gas which caused the ...

    Text Solution

    |

  9. The conjugate base of (CH3) NH2^(o+) is :

    Text Solution

    |

  10. Which of the following is the weakest base ?

    Text Solution

    |

  11. Which of the following reaction does not yield amine?

    Text Solution

    |

  12. Primary and secondary amines are distinguished by :

    Text Solution

    |

  13. Indicate which nitrogen compound amongst the following would undergo H...

    Text Solution

    |

  14. Pick up the correct stament :

    Text Solution

    |

  15. The producet of the reaction of alcoholic silver nitrite with ethyl br...

    Text Solution

    |

  16. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

    Text Solution

    |

  17. Azoxybenzene can be obtained by the treatment of mitro-benzene with :

    Text Solution

    |

  18. Tertiary nitro compounds cannot show tautomerism becauses :

    Text Solution

    |

  19. Diazo coupling is useful to prepare some

    Text Solution

    |

  20. The following reaction constituts : RNH2 + S=C=S overset (HgCl2) (r...

    Text Solution

    |