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The electrolytic reduction of nitrobenze...

The electrolytic reduction of nitrobenzene in strongly acidic medium produces .

A

Phenol

B

p-Aminophenol

C

Hydroazobenzen

D

Azohebzene

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The correct Answer is:
To solve the question regarding the electrolytic reduction of nitrobenzene in a strongly acidic medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: The starting compound is nitrobenzene (C6H5NO2). It contains a nitro group (-NO2) attached to a benzene ring. 2. **Understand the Reaction Conditions**: The reaction occurs in a strongly acidic medium, which can influence the reduction process. 3. **Electrolytic Reduction**: In an electrolytic reduction, nitrobenzene will undergo a reduction process where it loses oxygen. The nitro group (-NO2) is reduced to a nitroso group (-NO) first. 4. **Formation of Nitrosobenzene**: The first product of this reduction is nitrosobenzene (C6H5NO), which is formed by the loss of one oxygen atom from nitrobenzene. 5. **Further Reduction**: The nitrosobenzene can undergo further reduction, where it is converted to phenylhydroxylamine (C6H5NHOH). This involves the addition of hydrogen to the nitroso group. 6. **Rearrangement**: The phenylhydroxylamine can then rearrange to form para-aminophenol (C6H4(OH)(NH2)), where the hydroxyl group (-OH) and the amino group (-NH2) are positioned para to each other on the benzene ring. 7. **Final Product**: The final product of the electrolytic reduction of nitrobenzene in a strongly acidic medium is therefore para-aminophenol. ### Conclusion: The answer to the question is **option B: para-aminophenol**.

To solve the question regarding the electrolytic reduction of nitrobenzene in a strongly acidic medium, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant**: The starting compound is nitrobenzene (C6H5NO2). It contains a nitro group (-NO2) attached to a benzene ring. 2. **Understand the Reaction Conditions**: The reaction occurs in a strongly acidic medium, which can influence the reduction process. ...
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CENGAGE CHEMISTRY ENGLISH-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP-Exercises Single Correct
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