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A compound (X) has the molecular formula...

A compound (X) has the molecular formula ` C_3 H_7 NO` . With ` Br_2` and ` KOH`, (X) gives (Y) . (Y) responds to mustard oil reaction . (Y) upon treatment with ` HNO_2` evolves `N_2` and gives an alcohol (Z) which gives iodoform test , (X) is likelty to be :

A

`C_2H_5CONH_2`

B

`CH_3COHH_2`

C

`CH_3COONH_4`

D

`C_2H_5CNO`

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The correct Answer is:
To solve the problem step-by-step, we need to analyze the information given and deduce the structure of compound (X) based on its reactions and properties. ### Step 1: Identify the molecular formula and possible structures The molecular formula of compound (X) is C₃H₇NO. This indicates that (X) could be an amide, amine, or another nitrogen-containing organic compound. Given that it reacts with Br₂ and KOH, we can infer that it is likely an amide. **Hint:** Look for functional groups that match the molecular formula and consider common reactions involving nitrogen compounds. ### Step 2: Reaction with Br₂ and KOH The reaction of (X) with Br₂ and KOH suggests a Hofmann degradation reaction, which typically involves the conversion of an amide to a primary amine with one less carbon atom. Thus, if (X) is an amide, it will yield a primary amine (Y). **Hint:** Recall that Hofmann degradation reduces the carbon chain by one carbon atom and produces a primary amine. ### Step 3: Determine the structure of (X) Since (X) is likely an amide and has three carbons, the most plausible structure is propanamide (C₂H₅CONH₂). This structure fits the molecular formula C₃H₇NO. **Hint:** Consider the simplest amide structures that fit the molecular formula. ### Step 4: Identify compound (Y) Upon Hofmann degradation, propanamide (X) will yield ethylamine (C₂H₅NH₂) as compound (Y). Ethylamine is a primary amine, which is consistent with the mustard oil reaction. **Hint:** Primary amines react with carbon disulfide to give isothiocyanates, which have a characteristic odor. ### Step 5: Reaction of (Y) with HNO₂ When ethylamine (Y) is treated with nitrous acid (HNO₂), it produces ethanol (Z) and nitrogen gas (N₂). This reaction is characteristic of primary amines. **Hint:** Remember that primary amines react with nitrous acid to form alcohols and nitrogen gas. ### Step 6: Identify compound (Z) Ethanol (C₂H₅OH) is the alcohol produced (Z) from the reaction of ethylamine with HNO₂. Ethanol is known to give a positive iodoform test, which is another clue confirming our findings. **Hint:** The iodoform test is positive for alcohols with the structure R-CO-CH₃. ### Conclusion Based on the deductions made through the steps, we can conclude that compound (X) is propanamide (C₂H₅CONH₂). **Final Answer:** (X) is likely to be propanamide.

To solve the problem step-by-step, we need to analyze the information given and deduce the structure of compound (X) based on its reactions and properties. ### Step 1: Identify the molecular formula and possible structures The molecular formula of compound (X) is C₃H₇NO. This indicates that (X) could be an amide, amine, or another nitrogen-containing organic compound. Given that it reacts with Br₂ and KOH, we can infer that it is likely an amide. **Hint:** Look for functional groups that match the molecular formula and consider common reactions involving nitrogen compounds. ### Step 2: Reaction with Br₂ and KOH ...
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CENGAGE CHEMISTRY ENGLISH-ORGANIC COMPOUNDS WITH FUNCTIONAL GROUP-Exercises Single Correct
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  2. Which of the following represents the poinsonous gas which caused the ...

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  3. The conjugate base of (CH3) NH2^(o+) is :

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  4. Which of the following is the weakest base ?

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  5. Which of the following reaction does not yield amine?

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  6. Primary and secondary amines are distinguished by :

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  7. Indicate which nitrogen compound amongst the following would undergo H...

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  8. Pick up the correct stament :

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  9. The producet of the reaction of alcoholic silver nitrite with ethyl br...

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  10. The electrolytic reduction of nitrobenzene in strongly acidic medium p...

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  11. Azoxybenzene can be obtained by the treatment of mitro-benzene with :

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  12. Tertiary nitro compounds cannot show tautomerism becauses :

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  13. Diazo coupling is useful to prepare some

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  14. The following reaction constituts : RNH2 + S=C=S overset (HgCl2) (r...

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  15. Primary , secondary , tertiary amines can be separated by the followin...

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  16. When C6 H5N2Cl is reduced with Na 2 SnOO2, the product is :

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  17. Nitrogen is likely to be evolved when NaNO2 in dilute HCl warmed with...

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  18. A compound X has the molecular formula C(7)H(7)NO. On treatment with B...

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  19. A compound (X) has the molecular formula C3 H7 NO . With Br2 and KO...

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  20. An amine on treatment with HNO2 evolved N2 The amine on exhaustive me...

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