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Which of the following statements are co...

Which of the following statements are correct about Nylon-`6,6`?

A

Nylon fibers have higher tensile strenght than terylene fibers.

B

Nylon fibers have lower tensile strenght than terylene fibers.

C

In nylon, there is strong ihntermolecular `H`-bonding, while in trylene there is weak dipole-dipole interaction

D

In nylon, there is weak ihntermolecular `H`-bonding, while in trylene there is strong dipole-dipole interaction

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements about Nylon-6,6 are correct, we will analyze the properties of Nylon-6,6 and compare them with Terylene (also known as polyester). Here’s a step-by-step solution: ### Step 1: Understand the Composition of Nylon-6,6 Nylon-6,6 is a synthetic polymer made from hexamethylenediamine and adipic acid. It has a repeating unit that contains both amide (NH-CO) linkages, which are responsible for its properties. **Hint:** Remember that the presence of NH-CO bonds in Nylon-6,6 contributes to its strong intermolecular hydrogen bonding. ### Step 2: Analyze Mechanical Strength Nylon-6,6 is known for its high mechanical strength and superior resistance to wear and organic chemicals. It has more than double the strength and stiffness compared to unreinforced nylon. **Hint:** Consider how the structure of Nylon-6,6 contributes to its mechanical properties. ### Step 3: Compare with Terylene Terylene, on the other hand, does not have the same type of hydrogen bonding as Nylon-6,6. Instead, it primarily exhibits weak dipole-dipole interactions due to its ester linkages. **Hint:** Focus on the types of intermolecular forces present in both polymers to understand their differences. ### Step 4: Evaluate the Statements Now, let's evaluate the given statements: 1. **Nylon fiber has higher tensile strength than Terylene fiber.** - This statement is **incorrect**. While Nylon-6,6 is strong, Terylene fibers are also known for their strength, and the comparison can vary based on specific conditions. 2. **In Nylon, there is strong intermolecular H bonding while in Terylene there is weak dipole-dipole interaction.** - This statement is **correct**. Nylon-6,6 has strong hydrogen bonding due to its amide groups, while Terylene has weaker interactions. 3. **In Nylon, there is weak intermolecular H bonding while in Terylene there is strong dipole-dipole interaction.** - This statement is **incorrect**. Nylon-6,6 has strong hydrogen bonding, contradicting this statement. ### Conclusion Based on the analysis: - The correct statement is: **In Nylon, there is strong intermolecular H bonding while in Terylene there is weak dipole-dipole interaction.** ### Summary of Correct Statements - Only the second statement is correct.
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CENGAGE CHEMISTRY ENGLISH-SYNTHETIC AND NATURAL POLYMERS-Exercises Multiple Correct
  1. Which of the following are polyamide polymers?

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  2. Which of the following are polycarbamate ester polymers?

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  3. Which of the following statements are correct about Nylon-6,6?

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  4. Which of the following statements are correct about phenol-formaldehyd...

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  5. Which of the following are biodegradabe polymers?

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  6. Which of the following are used as free radical chain initiators?

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  7. Which of the following are used as chain transfer agents?

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  8. Nylon-5-10can be prepared by:

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  9. Nylon-5-10can be prepared by:

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  10. Which monomer would polymerise in isotactic syndiotactic and atactic f...

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  11. Polymerisation of buta-1,3diene by free radical mechanism gives:

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  12. Which of the following are biopolymers?

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  13. Which of the following are condensation copolymers?

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  14. Which of the following are additional homopolymers?

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  15. Which of the following fibres are made of polyamides?

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  16. Which of the following polymers contain1,3,-butadiene as one of the mo...

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  17. Which of the following are biodegradabe polymers?

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  18. Polymersation may occur through intermediate formation of:

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  19. Which of the following processes can be used to prepare polystyrene?

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  20. Which of the following are not thermosetting polymers?

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