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Which statements are correct about sucro...

Which statements are correct about sucrose?

A

IUPAC name of sucrose is `alpha`-D-glucopyranosyl-`beta`-D-fructofuranside.

B

IUPAC name of sucrose is `beta`-D-fructofuranosyl-`alpha`-D-glucopyranoside.

C

It is hydrolysed both by emulsin and amylase.

D

On hydrolysis, the solution is laevorotatory.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements are correct about sucrose, we will analyze each statement based on the structure and properties of sucrose. ### Step-by-Step Solution: 1. **Understanding the Structure of Sucrose**: - Sucrose is a disaccharide composed of glucose and fructose. - Glucose forms a six-membered ring (pyranose structure), while fructose forms a five-membered ring (furanose structure). - The linkage between glucose and fructose in sucrose is an α-1,2-glycosidic bond. 2. **Identifying the Correct IUPAC Name**: - The correct IUPAC name for sucrose is α-D-glucopyranosyl-β-D-fructofuranoside. - This name reflects the structures of both monosaccharides and the type of glycosidic bond formed. 3. **Evaluating Statement 1**: - Statement A: "The IUPAC name is α-D-glucopyranosyl-β-D-fructofuranoside." - This statement is correct as it accurately describes the structure and naming of sucrose. 4. **Evaluating Statement 2**: - Statement B: "The IUPAC name is β-D-glucopyranosyl-α-D-fructofuranoside." - This statement is incorrect because the order of the components and the suffixes are wrong. The correct order is α-D-glucopyranosyl followed by β-D-fructofuranoside. 5. **Evaluating Statement 3**: - Statement C: "Sucrose is hydrolyzed by amylase." - This statement is correct. Sucrose can be hydrolyzed by enzymes such as amylase, which breaks it down into glucose and fructose. 6. **Evaluating Statement 4**: - Statement D: "On hydrolysis, sucrose produces a mixture of glucose and fructose, which has a net levorotatory specific rotation." - This statement is also correct. The hydrolysis of sucrose results in a mixture of glucose and fructose, which exhibits a negative specific rotation (levorotatory) due to the inversion of rotation that occurs during hydrolysis. ### Conclusion: Based on the evaluations: - **Correct Statements**: A, C, and D. - **Incorrect Statement**: B. Thus, the final answer is that statements A, C, and D are correct about sucrose.
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