Home
Class 11
CHEMISTRY
Arrange the following alcohols in the de...

Arrange the following alcohols in the decreasing order of their ease of dehydration with `H_(2)SO_(4)`.
`a.`
`b.`
`c.`
`d.`
`e.`

Text Solution

Verified by Experts

Both the the options `(b)` and `(c)` are ` 3 ^(@)` alcohols, but in `(c)`, `3^(@)` carbocation is more stable due to resonance and gives a more substituted alkens .
`b.`
c.
Similarly, both (a) and (d) are `2^(@)` alcohols, but in (d), `2^(@)` carbocation can be stabilised to `3^(@) C^(o+)` via `1,2-H^(o-)` shift and gives more substituted alkene.
4.
So, the ease of dehydration is `:`
`(c) gt (b) gt (d) gt (a) gt (e)`
Promotional Banner

Topper's Solved these Questions

  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise SOLVED Example|62 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise EXERCISES|29 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives|13 Videos
  • ALKYNES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives - Analytical and Desriptive Type)|4 Videos

Similar Questions

Explore conceptually related problems

Arrange the following in the decreasing order of their acidity.

Arrange the following alcohols in the decreasing order of dehydration with conc. H_(2)SO_(4) .

Arrange the following in decreasing order of their C=C bond length

Arrange the following in decreasing order of stability

Arrange the following in decreasing order of stability

Arrange the following in decreasing order of acidity

Arrange the following Li, K, Na, H [In the decreasing order of their ionization potential].

Arrange reactivity of given alcohols in decreasing order for dehydration reaction with concentrated H_(2)SO_(4)