Home
Class 11
CHEMISTRY
Complete the following reactions : a. ...

Complete the following reactions `:`
`a.`
`b.`
`c.`

Text Solution

Verified by Experts

a.
b.
Although product `(Z)` is formed by Saytzeff's elimination, but the product `(Y)` is formed in major amount because product `(Y)` is a more stable conjugated diene than `(Z)`, isolater diene.
c.
d.
e.
f.

`g.`
If `1 mol` of `H_(2)O` is eliminated, a more stable Saytzeff product is formed, which undergoes tautomerism to give ketone.

So, compound `(X)` is not used for the preparation of buta `-13-`diene because a more stable product butan`-2-`one is formed.
`h.`
`i.`
`j.`
`k.` Base `(overset(ddot)overset(Θ)(B),e.g., overset(ddot)overset(Θ)(N)H_(2)" or "C_(2)H_(5)overset(ddot)overset(Θ)(O))` removes a proton, leaveing the anion, which is resoanace stabilised, as shown below.
Hence propyne is more stable than cumulative diene `(A)`. The heat of hydrogenation of allene `(A)` is `-298 kJ mol^(-1)`, whereas that of propyne is `-290 k J mol ^(-1)`.
The more negative is the value of hydrogenation, the less stable is the diene.
Promotional Banner

Topper's Solved these Questions

  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise SOLVED Example|62 Videos
  • ALKENES AND ALKADIENES

    CENGAGE CHEMISTRY ENGLISH|Exercise EXERCISES|29 Videos
  • ALKANES AND CYCLOALKANES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives|13 Videos
  • ALKYNES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives - Analytical and Desriptive Type)|4 Videos

Similar Questions

Explore conceptually related problems

Complete the following reactions : i. ii.

Complete the following reactions : i. ii.

1. Complete the following reactions: a.

Complete the following reaction: i. ii.

Complete the following reactions : C + H_2 rarr

Complete the following reaction equations :

Complete the following reactions: a. Identify (C)

Complete the following reactions : C_2H_4+O_2 rarr

Complete the following sequence of reactions :

Complete the following reactions : C_2H_4 + HBr rarr