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The total number of stereoisomers for (A...

The total number of stereoisomers for `(A)` is `:`

A

6

B

8

C

4

D

5

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The correct Answer is:
To determine the total number of stereoisomers for compound (A), we need to consider both geometrical (cis/trans) and optical isomers due to the presence of chiral centers. ### Step-by-Step Solution: 1. **Identify the Structure of Compound (A)**: - The compound has one double bond and two chiral centers. 2. **Count the Chiral Centers**: - In this case, there are 2 chiral centers. However, we also need to analyze the double bond. 3. **Analyze the Double Bond**: - The groups attached to the double bond are the same, which means we cannot use the formula \(2^n\) directly, where \(n\) is the number of stereocenters. 4. **Determine Geometrical Isomers**: - For the double bond, we can have cis and trans configurations. - The trans isomer can have different configurations at the chiral centers: - Chiral center 3 (C3) can be in the S configuration, and chiral center 6 (C6) can be in the R configuration, leading to one meso form. - The other configurations (C3 in R and C6 in S) will yield different optical isomers. - Therefore, for the trans isomer, we have 3 optical isomers (1 meso + 2 different). 5. **Count Isomers for the Cis Isomer**: - Similarly, for the cis isomer, we also have 3 optical isomers due to the same reasoning. 6. **Total Stereoisomers**: - Adding the stereoisomers from both configurations: - Trans isomer: 3 optical isomers - Cis isomer: 3 optical isomers - Total = 3 (trans) + 3 (cis) = 6 stereoisomers. ### Conclusion: The total number of stereoisomers for compound (A) is **6**. ---

To determine the total number of stereoisomers for compound (A), we need to consider both geometrical (cis/trans) and optical isomers due to the presence of chiral centers. ### Step-by-Step Solution: 1. **Identify the Structure of Compound (A)**: - The compound has one double bond and two chiral centers. 2. **Count the Chiral Centers**: ...
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CENGAGE CHEMISTRY ENGLISH-ALKENES AND ALKADIENES-Single Correct Answer Type
  1. Refer to Question. When the compound (B) on ozonolysis is followed by ...

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  2. trans -3,6-Dimethyl oct-4ene (A) exists in two diasteromer (I) and (II...

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  3. The total number of stereoisomers for (A) is :

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  4. An organic compound (A) (C(10)H(20))on reductive ozonolysis gives 2- m...

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  5. If the stereochemistry about the double bond in (A) is trans, two dias...

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  6. Compounds (B) and (C) are :

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  7. Compound (B) and (C) are :

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  8. The three compounds (A),(B),and (C) on hydrogenation with H(2)+Pd give...

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  9. Which of the following will have lower pK(a) value ?

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  10. The decreasing order of acidic character is :

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  11. Which of the following is the correct order of stability of the foll...

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  12. Which of the following is the most stable species ?

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  13. Which of the following is non - aromatic in nature ?

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  14. Which of the following species is least stable ?

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  15. Which of the following is anti- aromatic in nature ?

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  16. Intermediate (B) and Product (C) are :

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  17. Which statement is correct about cyclopentadienyl anion ?

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  18. In which of the following, the DeltaH(h)^(@) is maximum ?

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  19. Compound (C) is :

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  20. The decreasing order of reactivity towards electrophilic addition (e.g...

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