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Acid-catalysed hydration oxymercuration-...

Acid-catalysed hydration oxymercuration-demercu-ration, and hydroboration oxidation reaction will give the same product with:

A

a.But-2-ene

B

b.But-1-ene

C

c.

D

d.

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To determine which alkene will yield the same product from acid-catalyzed hydration, oxymercuration-demercuration, and hydroboration-oxidation reactions, we need to analyze the mechanisms of these reactions and how they apply to the given alkenes. ### Step-by-Step Solution: 1. **Understand the Reactions**: - **Acid-Catalyzed Hydration**: This reaction adds water across the double bond of the alkene. The OH group attaches to the more substituted carbon (Markovnikov's rule). - **Oxymercuration-Demercuration**: This involves the addition of mercury acetate (Hg(OAc)2) followed by reduction. It also follows Markovnikov's rule, where the OH group attaches to the more substituted carbon. - **Hydroboration-Oxidation**: This reaction involves the addition of borane (BH3) followed by oxidation. It follows anti-Markovnikov's rule, where the OH group attaches to the less substituted carbon. 2. **Identify the Alkene**: - We need to find an alkene where both Markovnikov and anti-Markovnikov products yield the same alcohol. This typically occurs when the alkene is symmetrical, meaning both carbons involved in the double bond have the same number of hydrogen atoms. 3. **Evaluate the Options**: - **Option A: 2-Butene**: This is a symmetrical alkene. In both reactions, the OH group will attach to the same carbon, yielding 2-butanol. - **Option B: 1-Butene**: This is not symmetrical. The products will differ between the two reactions. - **Option C: Cyclopentene with a side chain**: The products will differ due to the asymmetry of the double bond. - **Option D: Cyclopentene with a methyl side chain**: Similar to option C, the products will differ. 4. **Conclusion**: - The only alkene that gives the same product from both oxymercuration-demercuration and hydroboration-oxidation is **2-butene** (option A), which yields 2-butanol in both cases. ### Final Answer: **Option A: 2-Butene** gives the same product in acid-catalyzed hydration, oxymercuration-demercuration, and hydroboration-oxidation reactions.

To determine which alkene will yield the same product from acid-catalyzed hydration, oxymercuration-demercuration, and hydroboration-oxidation reactions, we need to analyze the mechanisms of these reactions and how they apply to the given alkenes. ### Step-by-Step Solution: 1. **Understand the Reactions**: - **Acid-Catalyzed Hydration**: This reaction adds water across the double bond of the alkene. The OH group attaches to the more substituted carbon (Markovnikov's rule). - **Oxymercuration-Demercuration**: This involves the addition of mercury acetate (Hg(OAc)2) followed by reduction. It also follows Markovnikov's rule, where the OH group attaches to the more substituted carbon. - **Hydroboration-Oxidation**: This reaction involves the addition of borane (BH3) followed by oxidation. It follows anti-Markovnikov's rule, where the OH group attaches to the less substituted carbon. ...
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Hydration reaction of alkene is catalyzed by dilute acid. Selection of acid is important . Conjugate base of the acid should not interfere in the reaction. There are other means by which alkenes can be converted to alcohols. Oxymercuration demercuration gives Markovnikoff's alcohols while hydroboration oxidation give Anti Markovnikoff's alcohol. The reagent required to perform the given transformation is