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Oxidation of aldehyde and ketone by pero...

Oxidation of aldehyde and ketone by peroxybenzoic acid to ester is called:

A

a.Elbs oxidation

B

b.Hell-Volhard-Zelinsky oxidation

C

c.Oppenaur oxidation

D

d.Baeyer-Villiger oxidation

Text Solution

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The correct Answer is:
To solve the question regarding the oxidation of aldehydes and ketones by peroxybenzoic acid to form esters, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reaction involves aldehydes (RCHO) and ketones (R2C=O) being oxidized by peroxybenzoic acid (PhC(O)OOH). 2. **Understand the Reaction Mechanism**: - When aldehydes or ketones react with peroxybenzoic acid, they undergo a transformation where the carbonyl group (C=O) is oxidized, leading to the formation of esters (RCOOR'). 3. **Recognize the Type of Reaction**: - This specific reaction is a type of oxidation where the carbonyl compounds are converted to esters through the addition of the peroxy group (OOH) from peroxybenzoic acid. 4. **Determine the Name of the Reaction**: - The oxidation of aldehydes and ketones by peroxybenzoic acid is specifically known as the **Baeyer-Villiger oxidation**. This is a well-known reaction in organic chemistry. 5. **Eliminate Other Options**: - The other options provided (Allylic oxidation, HVZ reaction, and open air oxidation) do not correspond to the reaction described in the question. - Allylic oxidation involves different reagents, HVZ reaction involves halogenation, and open air oxidation involves the oxidation of alcohols. 6. **Conclude the Answer**: - Therefore, the correct answer to the question is **Baeyer-Villiger oxidation**. ### Final Answer: The oxidation of aldehyde and ketone by peroxybenzoic acid to ester is called **Baeyer-Villiger oxidation**. ---

To solve the question regarding the oxidation of aldehydes and ketones by peroxybenzoic acid to form esters, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reaction involves aldehydes (RCHO) and ketones (R2C=O) being oxidized by peroxybenzoic acid (PhC(O)OOH). 2. **Understand the Reaction Mechanism**: ...
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