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Barium adipate overset(Dry distillation)...

`Barium adipate overset(Dry distillation)(rarr)(A)overset(MeCO_(3)H)(rarr)(B)`
The compounds `(A)` and `(B)`, respectively, are:

A

a.

B

b.

C

c.

D

d.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will follow these steps: ### Step 1: Identify the structure of Barium Adipate Barium adipate is a barium salt of adipic acid, which has the formula \( \text{Ba(C}_6\text{H}_{10}\text{O}_4) \). It consists of a six-carbon chain with two carboxylic acid groups at each end. ### Step 2: Dry Distillation of Barium Adipate When barium adipate undergoes dry distillation, it decomposes to form barium carbonate and cyclopentanone. The reaction can be summarized as follows: \[ \text{Barium adipate} \xrightarrow{\text{Dry Distillation}} \text{Cyclopentanone} + \text{BaCO}_3 \] ### Step 3: Determine Compound A From the dry distillation of barium adipate, we obtain cyclopentanone. Thus, compound A is: \[ \text{Compound A} = \text{Cyclopentanone} \] ### Step 4: Reaction with Peroxy Acid Next, we add peroxy acid (specifically, MeCO3H) to compound A (cyclopentanone). This reaction is known as Baeyer-Villiger oxidation, which converts ketones into esters or lactones. ### Step 5: Determine Compound B The reaction of cyclopentanone with peroxy acid results in the formation of a six-membered lactone. The structure of compound B can be represented as follows: \[ \text{Compound B} = \text{Cyclohexanone} \text{ (or a related lactone structure)} \] ### Conclusion Thus, the compounds (A) and (B) are: - Compound A: Cyclopentanone - Compound B: A six-membered lactone derived from cyclopentanone. ### Final Answer - Compound A: Cyclopentanone - Compound B: A six-membered lactone

To solve the question, we will follow these steps: ### Step 1: Identify the structure of Barium Adipate Barium adipate is a barium salt of adipic acid, which has the formula \( \text{Ba(C}_6\text{H}_{10}\text{O}_4) \). It consists of a six-carbon chain with two carboxylic acid groups at each end. ### Step 2: Dry Distillation of Barium Adipate When barium adipate undergoes dry distillation, it decomposes to form barium carbonate and cyclopentanone. The reaction can be summarized as follows: \[ \text{Barium adipate} \xrightarrow{\text{Dry Distillation}} \text{Cyclopentanone} + \text{BaCO}_3 \] ...
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