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overset(H(2)+Ni)(leftarrow) PhNO(2) over...

`overset(H_(2)+Ni)(leftarrow) PhNO_(2) overset(LAH)(rarr)(A)`.
The products `(A)` and `(B)` are:

A

a.`PhNH_(2)`, `PhNH_(2)`

B

b.`Ph-N=N-Ph`, `Ph-N=N-Ph`

C

c.`Ph-N=N-Ph, PhNH_(2)`

D

d.`Ph-NH-NH-Ph, PhNH_(2)`

Text Solution

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The correct Answer is:
To solve the question regarding the reduction of nitrobenzene using two different reducing agents, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactant:** The starting compound is nitrobenzene (PhNO₂). It has a nitro group (-NO₂) attached to a benzene ring. 2. **First Reducing Agent - Lithium Aluminum Hydride (LAH):** - Lithium aluminum hydride (LAH) is a strong reducing agent. - When nitrobenzene is treated with LAH, it undergoes reduction. - The nitro group (-NO₂) is reduced to an amine group (-NH₂), resulting in the formation of **azobenzene** (Ph-N=Ph). - Therefore, the product (A) from this reaction is **azobenzene**. 3. **Second Reducing Agent - Catalytic Hydrogenation (H₂ with Ni):** - The second method involves catalytic hydrogenation using hydrogen gas (H₂) in the presence of nickel (Ni) as a catalyst. - In this reaction, the nitro group (-NO₂) is reduced to an amine group (-NH₂) as well. - The product formed from this reaction is **aniline** (Ph-NH₂). - Therefore, the product (B) from this reaction is **aniline**. 4. **Summarize the Products:** - Product (A) from the reaction with LAH is **azobenzene**. - Product (B) from the reaction with H₂ and Ni is **aniline**. ### Final Answer: - Product (A) is **azobenzene**. - Product (B) is **aniline**.

To solve the question regarding the reduction of nitrobenzene using two different reducing agents, we can break down the process step by step. ### Step-by-Step Solution: 1. **Identify the Reactant:** The starting compound is nitrobenzene (PhNO₂). It has a nitro group (-NO₂) attached to a benzene ring. 2. **First Reducing Agent - Lithium Aluminum Hydride (LAH):** ...
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