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overset(NaBH(4))(leftarrow) PhCH=CH-CHOu...

`overset(NaBH_(4))(leftarrow) PhCH=CH-CHOunderset(2. H_(3)O^(+))overset(1. LAH, ether)(rarr)(A)`
The products `(A)` and `(B)` are:

A

a.

B

b.

C

c.

D

d.

Text Solution

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The correct Answer is:
To solve the problem, we need to identify the products (A) and (B) formed from the reduction of the given alpha-beta unsaturated aldehyde, PhCH=CH-CHO, using two different reducing agents: sodium borohydride (NaBH4) and lithium aluminum hydride (LiAlH4). ### Step-by-Step Solution: 1. **Identify the Structure of the Starting Compound**: The starting compound is PhCH=CH-CHO, which is an alpha-beta unsaturated aldehyde. Here, Ph represents a phenyl group (C6H5), CH=CH is the alkene part, and CHO is the aldehyde functional group. 2. **Reduction with Sodium Borohydride (NaBH4)**: - Sodium borohydride is a mild reducing agent. It primarily reduces aldehydes and ketones to their corresponding alcohols but does not affect alkenes. - In the case of PhCH=CH-CHO, NaBH4 will reduce the aldehyde (CHO) group to an alcohol (OH) while leaving the double bond (C=C) intact. - The product (B) formed after this reduction is PhCH=CH-CH2OH (where the aldehyde has been converted to an alcohol). 3. **Reduction with Lithium Aluminum Hydride (LiAlH4)**: - Lithium aluminum hydride is a strong reducing agent that can reduce both carbonyl groups (aldehydes and ketones) and alkenes. - In this case, LiAlH4 will reduce the aldehyde (CHO) group to an alcohol (OH) and also reduce the double bond (C=C) to a single bond (C-C). - The product (A) formed after this reduction is PhCH2-CH2-CH2OH (where both the aldehyde and the double bond have been reduced). ### Final Products: - Product (A): PhCH2-CH2-CH2OH - Product (B): PhCH=CH-CH2OH ### Summary: - (A) = PhCH2-CH2-CH2OH (reduced by LiAlH4) - (B) = PhCH=CH-CH2OH (reduced by NaBH4)

To solve the problem, we need to identify the products (A) and (B) formed from the reduction of the given alpha-beta unsaturated aldehyde, PhCH=CH-CHO, using two different reducing agents: sodium borohydride (NaBH4) and lithium aluminum hydride (LiAlH4). ### Step-by-Step Solution: 1. **Identify the Structure of the Starting Compound**: The starting compound is PhCH=CH-CHO, which is an alpha-beta unsaturated aldehyde. Here, Ph represents a phenyl group (C6H5), CH=CH is the alkene part, and CHO is the aldehyde functional group. 2. **Reduction with Sodium Borohydride (NaBH4)**: ...
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