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An aromatic compound (A), C(8)H(10), on ...

An aromatic compound `(A), C_(8)H_(10)`, on oxidation with acidic `KMnO_(4)` gives dibasic acid. The compound `(A)` on nitration gives three isomeric nitro derivatives. The compound (A) is:

A

a.o-Xylene

B

b.m-Xylene

C

c.p-Xylene

D

d.Ethyl benzene

Text Solution

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The correct Answer is:
To solve the question about the aromatic compound (A), C₈H₁₀, we will follow these steps: ### Step 1: Identify the structure of compound (A) Since compound (A) is an aromatic compound with the molecular formula C₈H₁₀, it must contain a benzene ring. The presence of two additional carbons (from the formula) suggests that there are two methyl groups attached to the benzene ring. The possible structures for C₈H₁₀ can be: - Ortho-xylene (1,2-dimethylbenzene) - Meta-xylene (1,3-dimethylbenzene) - Para-xylene (1,4-dimethylbenzene) ### Step 2: Analyze the oxidation reaction The question states that upon oxidation with acidic KMnO₄, compound (A) gives a dibasic acid. - Ortho-xylene and para-xylene would yield monobasic acids (benzoic acid) upon oxidation. - Meta-xylene, however, can be oxidized to isophthalic acid, which is a dibasic acid. ### Step 3: Analyze the nitration reaction The compound (A) also gives three isomeric nitro derivatives upon nitration. - Ortho-xylene would yield two isomers (ortho and para). - Para-xylene would yield only one isomer (para). - Meta-xylene would yield three isomers (one meta and two ortho). ### Step 4: Conclusion Since meta-xylene (1,3-dimethylbenzene) can be oxidized to isophthalic acid (a dibasic acid) and can produce three isomeric nitro derivatives upon nitration, we conclude that the compound (A) is **meta-xylene**. ### Final Answer The compound (A) is **meta-xylene** (1,3-dimethylbenzene). ---

To solve the question about the aromatic compound (A), C₈H₁₀, we will follow these steps: ### Step 1: Identify the structure of compound (A) Since compound (A) is an aromatic compound with the molecular formula C₈H₁₀, it must contain a benzene ring. The presence of two additional carbons (from the formula) suggests that there are two methyl groups attached to the benzene ring. The possible structures for C₈H₁₀ can be: - Ortho-xylene (1,2-dimethylbenzene) - Meta-xylene (1,3-dimethylbenzene) - Para-xylene (1,4-dimethylbenzene) ...
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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Single Correct)
  1. Toluene on reaction with CrO(3) and Ac(2)O gives benzaldehyde as the m...

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  2. The final product obtained in the oxidation of t-butyl benzene with Na...

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  3. An aromatic compound (A), C(8)H(10), on oxidation with acidic KMnO(4) ...

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  4. PhCH(2)CH(2)CH(3) underset((ii) h(2)O)overset((i) CrO(2)Cl(2)//C Cl(4)...

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  5. Identify (A) and *(B) in the reaction

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  6. The compound Me(3)C-NH(2) on oxidation with acidic KMnO(4) gives:

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  7. The product (A) is:

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  8. The product (A) and (B) are:

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  9. an Organic compound (A) (C(4)H(6)) forms a precipitate with Tollens an...

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  10. An alkene on ozonolysis yields only ethanal. There is an isomer of the...

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  11. (A) can be:

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  12. Which of the following is an incorrect statement?

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  13. (A) and (B) are:

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  14. The oxidation product of 1,2-cyclopentane diol with HIO(4) or (CH(3)CO...

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  15. Chromic anhydride in H(2)SO(4) is not blue by:

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  16. Which of the following reactions is correct?

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  17. Fehling's solution can make distinction between:

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  18. C(6)H(10)O(3) (Keto ester)(A)underset(Delta)overset(NaOH+I(2))(rarr) Y...

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  19. Suggest a suitable oxidising reagent for the following conversions:

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  20. C(2)H(5)O-overset(O)overset(||)(C )-OC(2)H(5) overset(2MeMgBr)(rarr) (...

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