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The oxidation product of 1,2-cyclopentan...

The oxidation product of `1,2`-cyclopentane diol with `HIO_(4)` or `(CH_(3)COO)_(4) Pb` is:

A

a.

B

b.

C

c.

D

d. None

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The correct Answer is:
To solve the question regarding the oxidation product of 1,2-cyclopentane diol with HIO₄ or (CH₃COO)₄Pb, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant:** The reactant is 1,2-cyclopentane diol, which has two hydroxyl (-OH) groups attached to the first and second carbon atoms of a cyclopentane ring. 2. **Understand the Oxidizing Agents:** The oxidizing agents mentioned are periodic acid (HIO₄) and lead tetraacetate [(CH₃COO)₄Pb]. Both of these reagents are known to cleave vicinal diols (diols with hydroxyl groups on adjacent carbons) and convert them into carbonyl compounds. 3. **Reaction Mechanism:** - When 1,2-cyclopentane diol reacts with periodic acid, the hydroxyl groups (-OH) will react with the oxidizing agent. - The reaction leads to the formation of a cyclic intermediate where the -OH groups are replaced by two carbonyl (C=O) groups. - Specifically, the -OH groups are oxidized, and water is eliminated, resulting in the formation of carbonyl groups. 4. **Formation of Carbonyl Compounds:** - The cleavage of the C-O bonds occurs, leading to the formation of two carbonyl groups (C=O) at the 1 and 2 positions of the cyclopentane ring. - This results in the formation of a diketone, specifically 1,2-cyclopentanedione. 5. **Final Product:** The final product of the oxidation of 1,2-cyclopentane diol with HIO₄ or (CH₃COO)₄Pb is **1,2-cyclopentanedione**. ### Conclusion: Thus, the oxidation product of 1,2-cyclopentane diol with HIO₄ or (CH₃COO)₄Pb is **1,2-cyclopentanedione**.

To solve the question regarding the oxidation product of 1,2-cyclopentane diol with HIO₄ or (CH₃COO)₄Pb, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant:** The reactant is 1,2-cyclopentane diol, which has two hydroxyl (-OH) groups attached to the first and second carbon atoms of a cyclopentane ring. 2. **Understand the Oxidizing Agents:** ...
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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Single Correct)
  1. Which of the following is an incorrect statement?

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  2. (A) and (B) are:

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  3. The oxidation product of 1,2-cyclopentane diol with HIO(4) or (CH(3)CO...

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  4. Chromic anhydride in H(2)SO(4) is not blue by:

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  5. Which of the following reactions is correct?

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  6. Fehling's solution can make distinction between:

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  7. C(6)H(10)O(3) (Keto ester)(A)underset(Delta)overset(NaOH+I(2))(rarr) Y...

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  8. Suggest a suitable oxidising reagent for the following conversions:

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  9. C(2)H(5)O-overset(O)overset(||)(C )-OC(2)H(5) overset(2MeMgBr)(rarr) (...

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  10. Which of the following compounds will not give haloform reaction?

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  11. Identify the set from the following which connot form acetone in a sin...

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  12. (A) will not

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  13. CH(3)CH(2)NO(2) underset(at 0^(@)C)overset(NaNO(2)+HBr)(rarr) (A). (A)...

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  14. Which of the following does not give Liebermann's nitroso reaction?

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  15. Of the following compounds, whose ozonolysis proves the Kekule structu...

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  16. CH(3)-overset(CH(3))overset(|)(CH)-NO(2) underset(at 0^(@)C)overset(Na...

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  17. Which of the following compounds are (A), (B), (C ), and (D)? Ph-ove...

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  18. The compound (A)

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  19. Fenton's regent (Fe^(2+)+H(2)O(2)) with benzene gives:

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  20. Lactic acid on oxidation with Fenton's reagent gives:

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