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Et-N^(o+)-=C^(ɵ) underset(or HgO or O(3)...

`Et-N^(o+)-=C^(ɵ) underset(or HgO or O_(3))overset(Cl_(2)+DMSO)(rarr)`. The compound `(A)` is:

A

a.Ethyl methyl amine

B

b.Ethylnitrile

C

c.Ethyl isocyanate

D

d.Ethyl cyanate

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The correct Answer is:
To solve the question regarding the reaction of ethyl isocyanide with various reagents, we will analyze the reactions step by step. ### Step 1: Identify the Reactant The reactant given is ethyl isocyanide, which can be represented as: \[ \text{C}_2\text{H}_5\text{N}^{\oplus} \equiv \text{C}^{\ominus} \] This structure indicates that ethyl isocyanide has a positive charge on nitrogen and a negative charge on carbon. ### Step 2: Determine the Reagents The reagents mentioned in the question are: 1. Chlorine (Cl₂) and Dimethyl Sulfoxide (DMSO) 2. Mercuric Oxide (HgO) 3. Ozone (O₃) ### Step 3: Analyze the Reaction with Chlorine and DMSO When ethyl isocyanide reacts with chlorine in the presence of DMSO, which is an oxidizing agent, it oxidizes the isocyanide to isocyanate. The reaction can be represented as follows: \[ \text{C}_2\text{H}_5\text{N} \equiv \text{C} + \text{Cl}_2 + \text{DMSO} \rightarrow \text{C}_2\text{H}_5\text{N} = \text{C} = \text{O} + \text{Cl}_2 \] The product formed is ethyl isocyanate: \[ \text{C}_2\text{H}_5\text{N} = \text{C} = \text{O} \] ### Step 4: Analyze the Reaction with Mercuric Oxide When ethyl isocyanide reacts with mercuric oxide (HgO), it also leads to the formation of ethyl isocyanate. The reaction can be represented as: \[ \text{C}_2\text{H}_5\text{N} \equiv \text{C} + \text{HgO} \rightarrow \text{C}_2\text{H}_5\text{N} = \text{C} = \text{O} + \text{Hg}_2\text{O} \] Here, mercuric oxide is reduced to mercurous oxide (Hg₂O). ### Step 5: Analyze the Reaction with Ozone When ethyl isocyanide reacts with ozone (O₃), it similarly produces ethyl isocyanate: \[ \text{C}_2\text{H}_5\text{N} \equiv \text{C} + \text{O}_3 \rightarrow \text{C}_2\text{H}_5\text{N} = \text{C} = \text{O} + \text{O}_2 \] In this case, ozone is reduced to oxygen gas. ### Conclusion In all three cases (with Cl₂ + DMSO, HgO, and O₃), the product formed is ethyl isocyanate (C₂H₅N=C=O). Therefore, the compound (A) is: \[ \text{Ethyl Isocyanate} \] ### Final Answer The compound (A) is **ethyl isocyanate**. ---

To solve the question regarding the reaction of ethyl isocyanide with various reagents, we will analyze the reactions step by step. ### Step 1: Identify the Reactant The reactant given is ethyl isocyanide, which can be represented as: \[ \text{C}_2\text{H}_5\text{N}^{\oplus} \equiv \text{C}^{\ominus} \] This structure indicates that ethyl isocyanide has a positive charge on nitrogen and a negative charge on carbon. ### Step 2: Determine the Reagents ...
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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Single Correct)
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  2. Identify the set from the following which connot form acetone in a sin...

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  3. (A) will not

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  4. CH(3)CH(2)NO(2) underset(at 0^(@)C)overset(NaNO(2)+HBr)(rarr) (A). (A)...

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  5. Which of the following does not give Liebermann's nitroso reaction?

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  6. Of the following compounds, whose ozonolysis proves the Kekule structu...

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  7. CH(3)-overset(CH(3))overset(|)(CH)-NO(2) underset(at 0^(@)C)overset(Na...

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  8. Which of the following compounds are (A), (B), (C ), and (D)? Ph-ove...

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  9. The compound (A)

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  10. Fenton's regent (Fe^(2+)+H(2)O(2)) with benzene gives:

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  11. Lactic acid on oxidation with Fenton's reagent gives:

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  12. The compounds (A) and (B) are:

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  13. (A) is:

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  14. The compound (A) is:

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  15. The compound (A) is:

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  16. Which single reagent can be used in the following conversions?

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  17. Et-N^(o+)-=C^(ɵ) underset(or HgO or O(3))overset(Cl(2)+DMSO)(rarr). Th...

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  18. Imines or enamines are selectively reduced to 1^(@) or 2^(@) amines wi...

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  19. Caprolactam on reduction with LAH or H(2)+Pt or Pd gives:

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  20. Caprolactam on reduction with LAH or H(2)+Pt or Pd gives:

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