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Caprolactam on reduction with LAH or H(2...

Caprolactam on reduction with `LAH` or `H_(2)+Pt` or `Pd` gives:

A

a.`4`-Amino butan-`1-ol`

B

b.`5`-Aminopentam-`1-ol`

C

c.`6`-Aminohexan-`1-ol`

D

d.`7`-Aminoheptan-`1-ol`

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The correct Answer is:
To solve the question regarding the reduction of caprolactam using lithium aluminium hydride (LAH) or hydrogen in the presence of platinum (Pt) or palladium (Pd), we can follow these steps: ### Step 1: Understand Caprolactam Structure Caprolactam is a cyclic amide with the formula C6H11NO. It contains a carbonyl group (C=O) and an amine group (–NH). The structure can be represented as follows: ``` O || NH-C-C-C-C-C ``` ### Step 2: Identify the Functional Groups In caprolactam, the carbonyl group (C=O) is the target for reduction. The amide functional group (–C(=O)NH–) will also be affected during the reduction process. ### Step 3: Apply the Reducing Agent When caprolactam is treated with LAH or hydrogen in the presence of a catalyst (Pt or Pd), the carbonyl group (C=O) will be reduced to an alcohol (–OH) group. The reaction can be summarized as follows: 1. The C=O bond will be cleaved. 2. The carbonyl carbon will be converted to a hydroxyl group (–OH). 3. The nitrogen atom will remain as part of the structure. ### Step 4: Draw the Product Structure After reduction, the structure of the product will look like this: ``` OH | NH-C-C-C-C-C ``` This indicates that the original carbonyl carbon now has an –OH group. ### Step 5: Count the Carbons and Identify the Alcohols The product retains the five carbon atoms from the original caprolactam, and now has two hydroxyl (–OH) groups. The structure can be numbered as follows: 1. The first carbon (C1) has an –OH group. 2. The fifth carbon (C5) also has an –OH group. ### Step 6: Determine the IUPAC Name The compound now has two hydroxyl groups, making it a diol. The IUPAC name can be derived as follows: - There are five carbons in the chain, which corresponds to "pentane." - Since there are two hydroxyl groups at positions 1 and 5, we denote it as "1,5-diol." Thus, the IUPAC name of the product is **pentane-1,5-diol**. ### Final Answer The correct product formed from the reduction of caprolactam with LAH or H2 in the presence of Pt or Pd is **pentane-1,5-diol**. ---

To solve the question regarding the reduction of caprolactam using lithium aluminium hydride (LAH) or hydrogen in the presence of platinum (Pt) or palladium (Pd), we can follow these steps: ### Step 1: Understand Caprolactam Structure Caprolactam is a cyclic amide with the formula C6H11NO. It contains a carbonyl group (C=O) and an amine group (–NH). The structure can be represented as follows: ``` O || ...
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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise (Single Correct)
  1. Which of the following compounds will not give haloform reaction?

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  2. Identify the set from the following which connot form acetone in a sin...

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  3. (A) will not

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  4. CH(3)CH(2)NO(2) underset(at 0^(@)C)overset(NaNO(2)+HBr)(rarr) (A). (A)...

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  5. Which of the following does not give Liebermann's nitroso reaction?

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  6. Of the following compounds, whose ozonolysis proves the Kekule structu...

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  7. CH(3)-overset(CH(3))overset(|)(CH)-NO(2) underset(at 0^(@)C)overset(Na...

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  8. Which of the following compounds are (A), (B), (C ), and (D)? Ph-ove...

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  9. The compound (A)

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  10. Fenton's regent (Fe^(2+)+H(2)O(2)) with benzene gives:

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  11. Lactic acid on oxidation with Fenton's reagent gives:

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  12. The compounds (A) and (B) are:

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  13. (A) is:

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  14. The compound (A) is:

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  15. The compound (A) is:

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  16. Which single reagent can be used in the following conversions?

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  17. Et-N^(o+)-=C^(ɵ) underset(or HgO or O(3))overset(Cl(2)+DMSO)(rarr). Th...

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  18. Imines or enamines are selectively reduced to 1^(@) or 2^(@) amines wi...

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  19. Caprolactam on reduction with LAH or H(2)+Pt or Pd gives:

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  20. Caprolactam on reduction with LAH or H(2)+Pt or Pd gives:

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