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Which of the following compound will giv...

Which of the following compound will give a yellow precipitate with iodine and alkali?

A

a.2-Hydroxy

B

b.Acetophenone

C

c.Methyl acetone

D

d.Acetone

Text Solution

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The correct Answer is:
To determine which of the given compounds will give a yellow precipitate with iodine and alkali, we need to identify compounds that can undergo the iodoform reaction. The iodoform reaction is characteristic of compounds that have a methyl ketone group (RCOCH3) or a secondary alcohol with a methyl group adjacent to the hydroxyl group (RCHOHCH3). ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - We need to look for compounds that have either a methyl ketone structure (RCOCH3) or a secondary alcohol with a methyl group (RCHOHCH3). 2. **Analyze Each Compound**: - **Option A**: Check if it has the functional unit RCOCH3 or RCHOHCH3. - **Option B**: Check for the same functional units. - **Option C**: Check if it has the required functional groups. - **Option D**: Check for the presence of the functional groups. 3. **Determine Which Compounds React**: - If a compound contains the functional group RCOCH3 (methyl ketone) or RCHOHCH3 (secondary alcohol), it will react with iodine and alkali to produce a yellow precipitate of iodoform (CHI3). 4. **Conclusion**: - After analyzing the options: - **Option A**: Contains the functional group, thus gives a yellow precipitate. - **Option B**: Contains the functional group, thus gives a yellow precipitate. - **Option C**: Does not contain the functional group, thus does not give a yellow precipitate. - **Option D**: Contains the functional group, thus gives a yellow precipitate. 5. **Final Answer**: The compounds that will give a yellow precipitate with iodine and alkali are **Option A, Option B, and Option D**.

To determine which of the given compounds will give a yellow precipitate with iodine and alkali, we need to identify compounds that can undergo the iodoform reaction. The iodoform reaction is characteristic of compounds that have a methyl ketone group (RCOCH3) or a secondary alcohol with a methyl group adjacent to the hydroxyl group (RCHOHCH3). ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - We need to look for compounds that have either a methyl ketone structure (RCOCH3) or a secondary alcohol with a methyl group (RCHOHCH3). 2. **Analyze Each Compound**: ...
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CENGAGE CHEMISTRY ENGLISH-REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS-Exercise Archives (Subjective)
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  17. When t-butanol and n-butanol are separately treated with a few drops o...

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  19. Identify (A), (B), and (C ) and give their strucyures.

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