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Under Wolff-Kishner reduction conditions...

Under Wolff-Kishner reduction conditions, the conversion which may be brought about is:

A

a.Benzophenone to diphenyl methane

B

b.Benzaldehyde to benzyl alcohol

C

c.Cyclohexanone to cyclohexane

D

d.Cyclohexanone to cyclohexanol

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The correct Answer is:
To solve the question regarding the conversions that can be achieved under Wolff-Kishner reduction conditions, we will analyze the process step by step. ### Step-by-Step Solution: 1. **Understanding Wolff-Kishner Reduction**: The Wolff-Kishner reduction is a method used to convert carbonyl groups (C=O) such as aldehydes and ketones into hydrocarbons. This reaction involves hydrazine (NH2NH2) and a strong base, typically potassium hydroxide (KOH), in a high-boiling solvent like ethylene glycol. 2. **General Reaction Mechanism**: - The carbonyl compound (either an aldehyde or a ketone) is treated with hydrazine (NH2NH2) to form a hydrazone intermediate. - Upon heating in the presence of a strong base, the hydrazone undergoes dehydrogenation, leading to the elimination of nitrogen gas (N2) and resulting in the formation of a hydrocarbon. 3. **Analyzing the Options**: - **Option A: Benzophenone to Dimethyl Diphenyl Methane**: - Benzophenone (C6H5)2C=O is treated with NH2NH2 and KOH. The carbonyl group is reduced to a methylene group (CH2), resulting in dimethyl diphenyl methane (C6H5)2CH2. This option is correct. - **Option B: Benzaldehyde to Benzyl Alcohol**: - Benzaldehyde (C6H5CHO) would undergo Wolff-Kishner reduction to form toluene (C6H5CH3), not benzyl alcohol (C6H5CH2OH). Therefore, this option is incorrect. - **Option C: Cyclohexanone to Cyclohexane**: - Cyclohexanone (C6H10O) is reduced to cyclohexane (C6H12) under Wolff-Kishner conditions. This option is correct. 4. **Final Conclusion**: The correct conversions under Wolff-Kishner reduction conditions are: - Option A: Correct (Benzophenone to Dimethyl Diphenyl Methane) - Option B: Incorrect (Benzaldehyde does not convert to Benzyl Alcohol) - Option C: Correct (Cyclohexanone to Cyclohexane) Thus, the correct answers are **A and C**.

To solve the question regarding the conversions that can be achieved under Wolff-Kishner reduction conditions, we will analyze the process step by step. ### Step-by-Step Solution: 1. **Understanding Wolff-Kishner Reduction**: The Wolff-Kishner reduction is a method used to convert carbonyl groups (C=O) such as aldehydes and ketones into hydrocarbons. This reaction involves hydrazine (NH2NH2) and a strong base, typically potassium hydroxide (KOH), in a high-boiling solvent like ethylene glycol. 2. **General Reaction Mechanism**: ...
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