Home
Class 12
CHEMISTRY
Arrange the folliwing compounds in incre...

Arrange the folliwing compounds in increasing order of `SN^(-1)` reactivity.
a. I.m `ClCH_(2)CH = CHCH_(2)CH_(3)`
II. `CH_(3)C(Cl) = CHCH_(2) CH_(3)`
III. `CH_(3)CH = CHCH_(2)CH_(2)Cl`
IV. `CH_(3)CH = CHCH_(2)(Cl) CH_(3)`
b. I. `CH_(3)CH_(2)Br`
II. `CH_(2) = CHCH(Br) CH_(3)`
III. `CH_(2) = CHBr`
IV. `CH_(3)CH (Br) CH_(3)`
C. I. `(CH_(3))_(3)CCl`, II. `C_(6)H_(5)C(CH_(3))_(2)Cl`
III. `(CH_(3))_(2)CHCl`, IV. `CH_(3)CH_(2)CH_(2)Cl`

Text Solution

AI Generated Solution

To arrange the given compounds in increasing order of SN1 reactivity, we need to analyze the structure of each compound and determine their reactivity based on the stability of the carbocation that would form during the SN1 reaction. The more stable the carbocation, the more reactive the compound will be in an SN1 reaction. ### Group A: 1. **Compound I: `ClCH2CH=CHCH2CH3`** - This is a primary allylic compound. The carbocation formed would be a primary allylic carbocation. 2. **Compound II: `CH3C(Cl)=CHCH2CH3`** - This is a vinylic compound. The carbocation formed would be a secondary allylic carbocation. 3. **Compound III: `CH3CH=CHCH2CH2Cl`** - This is a primary carbocation. The carbocation formed would be a primary carbocation. 4. **Compound IV: `CH3CH=CHCH2(Cl)CH3`** - This is a secondary allylic compound. The carbocation formed would be a secondary carbocation. ...
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective Type|5 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective|17 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples|21 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

Arrange the following compounds in increasing order of S_(N^1) reactivity. CH_3 CH_2 Br, CH_2 = CH CH (Br) CH_3, CH_3 CH (Br) CH_3

Arrange the following compounds in increasing order of S_(N^1) reactivity. ClCH_2 = CH CH_2CH_3, CH_3C (Cl) = CH CH_2 CH_3, CH_2 = CH CH_2 CH_2 Cl, CH_3CH = CH. CHCl CH_3 .

Arrange the following compounds in decreasing order of acidity. (i) ClCH_(2)CH_(2)CH_(2)COOH (ii) CH_(3)CHClCH_(2)COOH (iii) CH_(3)CH_(2)CHClCOOH

Arrange the folliwing halides in order of increasing SN^(2) and SN^(1) reactions. I. CH_(3)Cl , II. CH_(3)Br III. CH_(3)CH_(2)Cl , IV. (CH_(3))_(2)CHCl

The order of decreasing S_(N)1 reactivities of the halides (I ) CH_(3)CH_(2)CH_(2)Cl (II) CH_(2) = CHCHCICH_(3) (III) CH_(3)CH_(2)CHCICH_(3)

Arrange the following compounds in the increasing order of their boiling points: CH_(3)CH_(2)CH_(2)CHO, CH_(3)CH_(2)CH_(2)CH_(2)OH, H_(5)C_(2)-O-C_(2)H_(5),CH_(3)CH_(2)CH_(2)CH_(3)

Predict all order of reactivity of the following compounds in dehydrohalogenation. a,. I. CH_(3)CH_(2)CH_(2)CH_(2)Cl II. (CH_(3))_(2)CHCH_(2)Cl III. (CH_(3))_(2)CH - CH_(2)Br IV. CH_(3)CH(Br)CH_(2)CH_(3) V. (CH_(3))_(3) C - Br b. I. CH_(3)CH(Br)CH_(3) II. CH_(3)CH_(2)CH_(2)Br III. (CH_(3))_(2) CH - CH_(2) Br IV. (CH_(3))_(3)C - CH_(2) Br

Arrange the following halides in order of increasing S_N^(2) reactivity: CH_3Cl, CH_3Br , CH_3 CH_2 Cl, (CH_3)_2CHCl .

Correct order of reactivity - (A) CH_(2)=CH_(2)>CH_(3)-CH=CH_(2)>(CH_(3))_(2)C=CH_(2) (B) CH_(2)=CH_(2)>CH_(3)-CH=CH_(2) (C) CH_(2)=CH_(2) (D) CH_(3)-CH=CH_(2)

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Solved Problems
  1. Give the order of reactivity towards SN^(2) reaction of the followig: ...

    Text Solution

    |

  2. Give the order of reactivity towards SN^(1) reaction of the followig: ...

    Text Solution

    |

  3. Give the order of SN^(-1) of SN^(-1) and SN^(2) displacement of haloge...

    Text Solution

    |

  4. Give the order of reactivity towards E2 dehydrohalo-genation of the fo...

    Text Solution

    |

  5. Give the order of reactivity towards SN^(-1) solvoloysis of the follow...

    Text Solution

    |

  6. Give the order of reactivityh towards SN^(1) reaction of the following...

    Text Solution

    |

  7. Text Solution

    |

  8. Text Solution

    |

  9. Outline the preparationof the following compounds using a nucliphileic...

    Text Solution

    |

  10. Which compound in each of the following paris will react faster in SN^...

    Text Solution

    |

  11. Arrange the folliwing compounds in increasing order of SN^(-1) reactiv...

    Text Solution

    |

  12. Predict all the alkenes that would be formed by dehydrohalogenation of...

    Text Solution

    |

  13. Predict all order of reactivity of the following compounds in dehydroh...

    Text Solution

    |

  14. Explain : a. Vinyl chloride is unreactive in nucliphillic 4- subsitu...

    Text Solution

    |

  15. The nucliphilic substituation of primary alkyl chlorides wityh sodium ...

    Text Solution

    |

  16. Arrange the folliwing halides in order of increasing SN^(2) and SN^(1...

    Text Solution

    |

  17. Predicrt the order of reactivity of the following compounds in SN^(1) ...

    Text Solution

    |

  18. Predict the order of reactivity of the following compounds in S(n^(1))...

    Text Solution

    |

  19. Identify all the possible alkenes that would be formed on the dehydroh...

    Text Solution

    |

  20. Text Solution

    |