Home
Class 12
CHEMISTRY
The nucliphilic substituation of primary...

The nucliphilic substituation of primary alkyl chlorides wityh sodium acetate is cataysed by sodium iodide. Explain why.

Text Solution

Verified by Experts

`R - Cl + CH_(3) COONa rarr R - O overset(O) overset(||)(-C-)CH_(3) + NaCl`
This reaction is `SN^(2)`, Nucleophile is `CH_(3)COO^(o-)`.
But in alkyl chloride `(C-Cl)` is a strong bond and is difficult to break. But in teh presence of `Nal, (R-Cl)` is converted to `(R-1)` (Finkelstein reaction) and in `(R-1)`, the `(C-I)` bond is weak which can be easily cleaved, So `SN^(2)` reaction is cataysed in the presence of `Nal `R - Cl + Nal rarr R-1 + NaCl`
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective Type|5 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Subjective|17 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples|21 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

Reaction of ethyl chloride with sodium leads to :

What happens when sodium acetate is heated with sodalime

Calcium chloride reacting with sodium carbonate

Aqueous solution of sodium acetate is

Heating of sodium acetate with soda lime produces

The aqueous solution of sodium acetate is basic. Explain.

Sodium chloride is known as

Calculate the molar mass of sodium acetate.

Concentration of sodium and chloride ions is lowest

Concentration of sodium and chloride ions is lowest

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Solved Problems
  1. Give the order of reactivity towards SN^(2) reaction of the followig: ...

    Text Solution

    |

  2. Give the order of reactivity towards SN^(1) reaction of the followig: ...

    Text Solution

    |

  3. Give the order of SN^(-1) of SN^(-1) and SN^(2) displacement of haloge...

    Text Solution

    |

  4. Give the order of reactivity towards E2 dehydrohalo-genation of the fo...

    Text Solution

    |

  5. Give the order of reactivity towards SN^(-1) solvoloysis of the follow...

    Text Solution

    |

  6. Give the order of reactivityh towards SN^(1) reaction of the following...

    Text Solution

    |

  7. Text Solution

    |

  8. Text Solution

    |

  9. Outline the preparationof the following compounds using a nucliphileic...

    Text Solution

    |

  10. Which compound in each of the following paris will react faster in SN^...

    Text Solution

    |

  11. Arrange the folliwing compounds in increasing order of SN^(-1) reactiv...

    Text Solution

    |

  12. Predict all the alkenes that would be formed by dehydrohalogenation of...

    Text Solution

    |

  13. Predict all order of reactivity of the following compounds in dehydroh...

    Text Solution

    |

  14. Explain : a. Vinyl chloride is unreactive in nucliphillic 4- subsitu...

    Text Solution

    |

  15. The nucliphilic substituation of primary alkyl chlorides wityh sodium ...

    Text Solution

    |

  16. Arrange the folliwing halides in order of increasing SN^(2) and SN^(1...

    Text Solution

    |

  17. Predicrt the order of reactivity of the following compounds in SN^(1) ...

    Text Solution

    |

  18. Predict the order of reactivity of the following compounds in S(n^(1))...

    Text Solution

    |

  19. Identify all the possible alkenes that would be formed on the dehydroh...

    Text Solution

    |

  20. Text Solution

    |