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Compound (F) is:...


Compound `(F)` is:

A

B

C

D

Text Solution

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The correct Answer is:
`d`

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Four isomeric optically active compounds overset (NaHCO_3) rarr CO_2 (g) (A, B , C, D) (C_4 H_8 O_3) Compound (A) overset (LAH) rarr ( E) (Archiral compound) Compound (B) overset (KMnO_4) underset (or CrO_3) rarr Inert to oxidation. Compound ( C) underset (NaOI//H_3 O^(oplus)) rarr CHI_3 (Yellow ppt.) + Compound (F) . Compound ( C) is :

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"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (E) is.

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"Colemanite" + Na_(2)CO_(3) overset("Fused")rarr (A) + (B) + CO_(2) underset("Solution")((A)) + CO_(2) rarr(B) + Na_(2) CO_(3) (B) + conc HCl rarr NaCl + underset("Acid")((C)) underset("Acid")((C)) +H_(2)O rarr underset("Acid")((D)) (D) overset("Strong heating")rarr (E) (E) +CuSO_(4) overset("Heated") underset("inflame")rarr underset("Blue-coloured compound")((F)) . Compound (A) is.