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Compound (D) is:...


Compound `(D)` is:

A

B

C

D

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The correct Answer is:
`c`
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Match each of the following four structures with one of the compound A-D on the basis of the following experimental facts Compound (A),(B) and ( C ) are optically active, but compound (D) is not Compound (C ) gives the same products as compound (D) on treatment with periodic acid, But compound (B) gives a different product. Compound (A) does not react with periodic acid. Compound A-D are respectively?

When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic (C ) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.

When compound (A) is treated with conc. H_(2)SO_(4) , a reddish brown colour gas (B) is evolved. To this solution, a solution of (C ) is added slowly from the side of the test tube, a blue ring is obtained at the junction of two layers due to formation of (D). Compound (D) has formula :

An inorganic red coloured compound (A) on heating gives a compound (B) and a gas (C). (A) on treatment with dil. HNO_(3) gives compound (D), brown colour substnace (E) and a neutral oxide (F). Compound (D) on warming gives off again gas (C). Then, (E) will be

A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) and (C ) of manganese are formed. Compound (C ) reacts with KOH in the presence of potassium nitrate to give compound (B). On heating compound (C ) with conc. H_(2)SO_(4) and NaCl, chlorine gas is liberate and a compound (D) of manganese alongwith other products is formed. Identify compounds A to D and also explain the reaction involved.

ZnCI_(2)+NaHCO_(3)overset("Heat")rarr (A)overset("Heat")rarr (B)+(C )+H_(2)O (B)+NaOH rarr (D) Identify the compound (D) present in the solution.

(i) A powdered substance (A) on treatment with fusion mixture gives a green coloured compound (B). (ii) The solution of (B) in boiling water on acidification with dilute H_(2)SO_(4) gives a pink coloured compound (C ) . (iii) The aqueous solution of (A) on treatment with NaOH and Br_(2)- water gives a compound (D). (iv) A solution of (D) in conc. HNO_(3) on treatment with lead peroxide at boiling temperature produced a compound (E) which was of the same colour at that of (C) . Identify A , B ,C ,D , E

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. Compounds (B) and (C) respectively are:

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  2. Give the major product of the folliwng reaction.

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  3. Compound (D) is:

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  4. The above conversion can be carried out by which process.

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  5. Product (C) is:

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  6. In the follwing reactionsL the rate of reaction (I) and (II) are...

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  7. In which case will SE not be in m- position?

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  8. Which of the folliwng has the highest dipole moment?

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  9. Which of the following is the most stable carbonium or benzenium ion?

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  10. Which of the following ketonic compound is the least stable?

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  11. Which of the following compounds will give curdy precipate with AgNO(3...

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  12. Which of the folliwng compounds is the most reactive towards electroph...

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  13. Which of the folliwng is the most stable species?

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  14. Which of the following in not aromatic in nature?

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  15. Which of the following species will be least stable?

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  16. Which of the follwing compounds will undergo Friedel Creadfts alylatio...

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  17. Which of the following is anti-aromatic in nature?

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  18. Which of the following aromatic compounds is least reactive towards el...

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  19. Which of the folliwng compounds will show faster ArSN^(2) reactions?

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  20. Which of the folliwng is the order of the rate of reaction of C(6)H(6)...

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