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The decreaing basic order of the followi...

The decreaing basic order of the following is:
i. `overset(o-)(C)N`, ii. `overset(o-)(O)H`, iii. `overset(o-)(O) Me`, iv. `overset(o-)(C)H_(3)`, v. `H^(o-)`

A

`(v) gt (iv) gt (iii) gt (ii) gt (i)`

B

`(i) gt (ii) gt (iii) gt (iv) gt (v)`

C

`(iv) gt (v) gt (iii) gt (ii) gt (i)`

D

`(i) gt (ii) gt (iii) gt (v) gt (iv)`

Text Solution

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The correct Answer is:
To determine the decreasing basic order of the given species, we will analyze each species and its conjugate acid. The basic strength of a species is inversely related to the acidity of its conjugate acid. Thus, we will follow these steps: ### Step 1: Identify the Species The species given are: 1. \( \overset{o-}{C}N \) (Cyanide ion) 2. \( \overset{o-}{O}H \) (Hydroxide ion) 3. \( \overset{o-}{O}Me \) (Methoxide ion) 4. \( \overset{o-}{C}H_3 \) (Methyl anion) 5. \( H^{o-} \) (Hydride ion) ### Step 2: Determine the Conjugate Acids To find the basic strength, we need to determine the conjugate acids of each species: 1. For \( \overset{o-}{C}N \): Conjugate acid is HCN (Hydrogen cyanide) 2. For \( \overset{o-}{O}H \): Conjugate acid is H2O (Water) 3. For \( \overset{o-}{O}Me \): Conjugate acid is CH3OH (Methanol) 4. For \( \overset{o-}{C}H_3 \): Conjugate acid is CH4 (Methane) 5. For \( H^{o-} \): Conjugate acid is H2 (Hydrogen gas) ### Step 3: Assess the Acidity of the Conjugate Acids Now, we will assess the acidity of these conjugate acids: 1. HCN is a weak acid. 2. H2O is a neutral molecule. 3. CH3OH is a weak acid. 4. CH4 is a very weak acid (almost neutral). 5. H2 is a weak acid. ### Step 4: Rank the Acids from Strongest to Weakest Based on the acidity: 1. HCN (strongest acid) 2. CH3OH (more acidic than water) 3. H2O (neutral) 4. H2 (weak acid) 5. CH4 (least acidic) ### Step 5: Determine the Basic Strength Order The basic strength order of the original species will be the opposite of the acidity order of their conjugate acids: 1. \( \overset{o-}{C}H_3 \) (most basic, from CH4) 2. \( H^{o-} \) (from H2) 3. \( \overset{o-}{O}H \) (from H2O) 4. \( \overset{o-}{O}Me \) (from CH3OH) 5. \( \overset{o-}{C}N \) (least basic, from HCN) ### Final Order Thus, the decreasing basic order of the species is: \[ \overset{o-}{C}H_3 > H^{o-} > \overset{o-}{O}H > \overset{o-}{O}Me > \overset{o-}{C}N \]

To determine the decreasing basic order of the given species, we will analyze each species and its conjugate acid. The basic strength of a species is inversely related to the acidity of its conjugate acid. Thus, we will follow these steps: ### Step 1: Identify the Species The species given are: 1. \( \overset{o-}{C}N \) (Cyanide ion) 2. \( \overset{o-}{O}H \) (Hydroxide ion) 3. \( \overset{o-}{O}Me \) (Methoxide ion) 4. \( \overset{o-}{C}H_3 \) (Methyl anion) ...
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The decreasing fugacity order of the following is: i. overset(o-)(C)N , ii. overset(o-)(O)H , iii. overset(o-)(O) Me , iv. overset(o-)(C)H_(3) , v. H^(o-)

The decreasing basic order of the following is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The decreasing basic order of the following is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decreasing nucleophilic oder of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The deecreasing leaving group order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The decrasing fugacity order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decreasing nucelophilic order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decreasing basic order of the following is: i. PhSO_(3)^(o-) , ii. C_(2)H_(5)SO_(3)^(o-) , iii. C_(2)H_(5)COO^(o-) , iv. overset(o-)(C)N , v. overset(o-)(O)H

The decreasing fugacity order of the following compounds is: i. PhSO_(3)^(o-) , ii. C_(2)H_(5)SO_(3)^(o-) , iii. C_(2)H_(5)COO^(o-) , iv. overset(o-)(C)N , v. overset(o-)(O)H

Write IUPAC name of the following : H-overset(O)overset(||)C-O-H

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. The decreasing nucleophilic order of the following compounds is: i. ...

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  2. The decreasing fugacity order of the following compounds is: i. PhSO...

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  3. The decreaing basic order of the following is: i. overset(o-)(C)N, i...

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  4. The decreasing nucelophilc order of the following compounds is: i. o...

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  5. The decreasing fugacity order of the following is: i. overset(o-)(C)...

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  6. The decrasing basic order of the following is: i. Me(2)N - NMe(2), i...

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  7. Decreasing nucelophilic order of the following is: i. Me(2)N - Nme(2...

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  8. The decresing fugacity order of the following is: i. Me(2)N - Nme(2)...

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  9. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  10. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  11. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  12. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  13. CH(3) - CH(Cl) - C(2)H(5) overset(Alc.KOH)(rarr) CH(3) - CH = CH - CH(...

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  14. Alkyl halides can be obtained by all methods except

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  15. Neopentyl chloride on reaction with ethanolic KOH is likely to give

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  16. In the reaction CH(3)C equiv C^(-)Na^(+) + (CH(3))(2) CHCl rarr Prod...

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  17. In order to get ethanethiol from bromoethane, the reagent used is :

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  18. For the preparation of chloroethane,

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  19. X on treatment with sodium hydroxide followed by the addition of silve...

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  20. Which of the following cannot be used for the preaparation of iodofro...

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