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The decreasing fugacity order of the fol...

The decreasing fugacity order of the following is:
i. `overset(o-)(C)N`, ii. `overset(o-)(O)H`, iii. `overset(o-)(O) Me`, iv. `overset(o-)(C)H_(3)`, v. `H^(o-)`

A

`(v) gt (iv) gt (iii) gt (ii) gt (i)`

B

`(i) gt (ii) gt (iii) gt (iv) gt (v)`

C

`(iv) gt (v) gt (iii) gt (ii) gt (i)`

D

`(i) gt (ii) gt (iii) gt (v) gt (iv)`

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The correct Answer is:
To determine the decreasing fugacity order of the given anions, we need to analyze their basic strengths and relate them to their conjugate acids. The basic strength of an anion is inversely related to the strength of its conjugate acid; stronger conjugate acids correspond to weaker bases, which in turn means better leaving groups. Let's denote the anions as follows: 1. \( \overset{o-}{(C)N} \) (Cyanide ion, CN⁻) 2. \( \overset{o-}{(O)H} \) (Hydroxide ion, OH⁻) 3. \( \overset{o-}{(O)Me} \) (Methoxide ion, MeO⁻) 4. \( \overset{o-}{(C)H_3} \) (Methyl anion, CH₃⁻) 5. \( H^{(o-)} \) (Hydride ion, H⁻) ### Step 1: Identify the conjugate acids To find the conjugate acids, we add a proton (H⁺) to each anion: 1. For \( \overset{o-}{(C)N} \): \( CN^- + H^+ \rightarrow HCN \) 2. For \( \overset{o-}{(O)H} \): \( OH^- + H^+ \rightarrow H_2O \) 3. For \( \overset{o-}{(O)Me} \): \( MeO^- + H^+ \rightarrow MeOH \) 4. For \( \overset{o-}{(C)H_3} \): \( CH_3^- + H^+ \rightarrow CH_4 \) 5. For \( H^{(o-)} \): \( H^- + H^+ \rightarrow H_2 \) ### Step 2: Determine the acidic strength of the conjugate acids Now we compare the acidic strength of the conjugate acids: - \( HCN \) is the most acidic. - \( MeOH \) is more acidic than \( H_2O \). - \( H_2 \) is less acidic than \( CH_4 \). Thus, the order of acidic strength from strongest to weakest is: 1. \( HCN \) (most acidic) 2. \( MeOH \) 3. \( H_2O \) 4. \( H_2 \) 5. \( CH_4 \) (least acidic) ### Step 3: Determine the basic strength of the anions Since stronger acids correspond to weaker bases, we can reverse the order of acidic strength to determine the basic strength: 1. \( CH_3^- \) (strongest base) 2. \( H^- \) 3. \( OH^- \) 4. \( MeO^- \) 5. \( CN^- \) (weakest base) ### Step 4: Determine the fugacity order (leaving group strength) The fugacity order (or leaving group strength) is the reverse of the basic strength: 1. \( CN^- \) (best leaving group) 2. \( MeO^- \) 3. \( OH^- \) 4. \( H^- \) 5. \( CH_3^- \) (worst leaving group) ### Final Order Thus, the decreasing fugacity order of the anions is: 1. \( CN^- \) 2. \( MeO^- \) 3. \( OH^- \) 4. \( H^- \) 5. \( CH_3^- \) ### Answer The decreasing fugacity order of the given anions is: \[ CN^- > MeO^- > OH^- > H^- > CH_3^- \]

To determine the decreasing fugacity order of the given anions, we need to analyze their basic strengths and relate them to their conjugate acids. The basic strength of an anion is inversely related to the strength of its conjugate acid; stronger conjugate acids correspond to weaker bases, which in turn means better leaving groups. Let's denote the anions as follows: 1. \( \overset{o-}{(C)N} \) (Cyanide ion, CN⁻) 2. \( \overset{o-}{(O)H} \) (Hydroxide ion, OH⁻) 3. \( \overset{o-}{(O)Me} \) (Methoxide ion, MeO⁻) 4. \( \overset{o-}{(C)H_3} \) (Methyl anion, CH₃⁻) 5. \( H^{(o-)} \) (Hydride ion, H⁻) ...
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The decreaing basic order of the following is: i. overset(o-)(C)N , ii. overset(o-)(O)H , iii. overset(o-)(O) Me , iv. overset(o-)(C)H_(3) , v. H^(o-)

The decreasing basic order of the following is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The decreasing basic order of the following is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decrasing fugacity order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decreasing nucleophilic oder of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The deecreasing leaving group order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(N)H_(2) , iii. overset(o-)(O)H , iv. F^(o-)

The decreasing nucelophilic order of the following compounds is: i. overset(o-)(C)H_(3) , ii. overset(o-)(O)H , iii. CH_(3)COO^(o-) , iv. H_(2)O

The decreasing fugacity order of the following compounds is: i. PhSO_(3)^(o-) , ii. C_(2)H_(5)SO_(3)^(o-) , iii. C_(2)H_(5)COO^(o-) , iv. overset(o-)(C)N , v. overset(o-)(O)H

The decreasing basic order of the following is: i. PhSO_(3)^(o-) , ii. C_(2)H_(5)SO_(3)^(o-) , iii. C_(2)H_(5)COO^(o-) , iv. overset(o-)(C)N , v. overset(o-)(O)H

The decreasing nucleophilic order of the following compounds is: i. PhSO_(3)^(o-) , ii. C_(2)H_(5)SO_(3)^(o-) , iii. C_(2)H_(5)COO^(o-) , iv. overset(o-)(C)N , v. overset(o-)(O)H

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. The decreaing basic order of the following is: i. overset(o-)(C)N, i...

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  2. The decreasing nucelophilc order of the following compounds is: i. o...

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  3. The decreasing fugacity order of the following is: i. overset(o-)(C)...

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  4. The decrasing basic order of the following is: i. Me(2)N - NMe(2), i...

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  5. Decreasing nucelophilic order of the following is: i. Me(2)N - Nme(2...

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  6. The decresing fugacity order of the following is: i. Me(2)N - Nme(2)...

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  7. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  8. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  9. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  10. underset("Specific rotation" = +50^(@))(Ph-CH(OH)CH(3)) overset(SOCl(2...

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  11. CH(3) - CH(Cl) - C(2)H(5) overset(Alc.KOH)(rarr) CH(3) - CH = CH - CH(...

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  12. Alkyl halides can be obtained by all methods except

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  13. Neopentyl chloride on reaction with ethanolic KOH is likely to give

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  14. In the reaction CH(3)C equiv C^(-)Na^(+) + (CH(3))(2) CHCl rarr Prod...

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  15. In order to get ethanethiol from bromoethane, the reagent used is :

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  16. For the preparation of chloroethane,

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  17. X on treatment with sodium hydroxide followed by the addition of silve...

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  18. Which of the following cannot be used for the preaparation of iodofro...

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  19. Which of the following hladies is capable of exhibitin enantiomerism?

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  20. A suspension of CaOCl(2) in water is heated with ethanol, the product ...

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