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X on treatment with sodium hydroxide fol...

X on treatment with sodium hydroxide followed by the addition of silver nitrate give white precipitate at room temperature which are soluble in `NH_(4)OH`. X can be :

A

Chlorbenzene

B

Ethyl bromide

C

Benzyl chloride

D

Vinyl chloride

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The correct Answer is:
To solve the problem, we need to identify the compound X based on the given reactions and observations. Let's break it down step by step. ### Step 1: Understand the Reaction The problem states that compound X, when treated with sodium hydroxide (NaOH) and then silver nitrate (AgNO3), produces a white precipitate at room temperature. The white precipitate is soluble in ammonium hydroxide (NH4OH). ### Step 2: Identify the White Precipitate The white precipitate formed when silver nitrate is added to a solution containing chloride ions (Cl-) is silver chloride (AgCl). Therefore, we can conclude that compound X must be capable of releasing chloride ions when treated with NaOH. ### Step 3: Analyze Possible Compounds Now, let's analyze the potential candidates for compound X: 1. **Chlorobenzene (C6H5Cl)**: - Chlorobenzene does not react with NaOH to release Cl- due to the partial double bond character of the C-Cl bond. Therefore, it cannot produce AgCl. 2. **Ethyl Bromide (C2H5Br)**: - Ethyl bromide would release bromide ions (Br-) upon treatment with NaOH, leading to the formation of AgBr, which is a yellow precipitate. Thus, it cannot be the answer since we need a white precipitate. 3. **Benzyl Chloride (C6H5CH2Cl)**: - Benzyl chloride has a benzylic carbon, and when treated with NaOH, it can release chloride ions (Cl-). This would lead to the formation of AgCl, which is a white precipitate. Additionally, AgCl is soluble in ammonium hydroxide. 4. **Vinyl Chloride (C2H3Cl)**: - Vinyl chloride also has a C-Cl bond with partial double bond character, making it unreactive towards NaOH. Thus, it cannot produce AgCl. ### Step 4: Conclusion Based on the analysis, the only compound that fits all the criteria is **Benzyl Chloride (C6H5CH2Cl)**. It can release chloride ions when treated with NaOH, leading to the formation of a white precipitate of AgCl, which is soluble in ammonium hydroxide. ### Final Answer The compound X can be: **Benzyl Chloride (C6H5CH2Cl)**. ---

To solve the problem, we need to identify the compound X based on the given reactions and observations. Let's break it down step by step. ### Step 1: Understand the Reaction The problem states that compound X, when treated with sodium hydroxide (NaOH) and then silver nitrate (AgNO3), produces a white precipitate at room temperature. The white precipitate is soluble in ammonium hydroxide (NH4OH). ### Step 2: Identify the White Precipitate The white precipitate formed when silver nitrate is added to a solution containing chloride ions (Cl-) is silver chloride (AgCl). Therefore, we can conclude that compound X must be capable of releasing chloride ions when treated with NaOH. ...
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  8. Which of the following is a geminal dihalide ?

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  15. The reaction between chloral and chlorobenzene in H(2)SO(4) yields:

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