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The reaction between chloral and chlorob...

The reaction between chloral and chlorobenzene in `H_(2)SO_(4)` yields:

A

Chloretone

B

`p,p-` Dichlorodiphenyl trichloroenthane

C

`o-` Chlorobenzaldichloride

D

Chloralphenylchloride

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The correct Answer is:
To solve the question regarding the reaction between chloral and chlorobenzene in sulfuric acid (H₂SO₄), we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Chloral (CCl₃CHO) is an aldehyde with three chlorine atoms attached to the carbon. - Chlorobenzene (C₆H₅Cl) is a benzene ring with one chlorine atom attached. 2. **Understand the Reaction Medium**: - The reaction takes place in the presence of sulfuric acid (H₂SO₄), which acts as a catalyst and provides an acidic medium. 3. **Mechanism of Reaction**: - In the acidic medium, chloral can form a carbocation. The chlorine atoms in chlorobenzene can act as nucleophiles. - The reaction involves the electrophilic substitution of the chlorobenzene by the chloral. 4. **Formation of the Product**: - The chloral reacts with chlorobenzene to form a complex compound. The reaction leads to the formation of a compound known as para-dichlorodiphenyltrichloroethane (DDT). - This occurs through the removal of water (dehydration) and the formation of new carbon-carbon bonds. 5. **Final Product**: - The final product of the reaction is para-dichlorodiphenyltrichloroethane (DDT), which is represented as C₁₄H₉Cl₅. ### Conclusion: The reaction between chloral and chlorobenzene in H₂SO₄ yields para-dichlorodiphenyltrichloroethane (DDT).

To solve the question regarding the reaction between chloral and chlorobenzene in sulfuric acid (H₂SO₄), we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Chloral (CCl₃CHO) is an aldehyde with three chlorine atoms attached to the carbon. - Chlorobenzene (C₆H₅Cl) is a benzene ring with one chlorine atom attached. ...
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CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. Choose the incorrect reaction.

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  2. In order to convert aniline into chlorobenzene the reagents needed are

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  3. The reaction between chloral and chlorobenzene in H(2)SO(4) yields:

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  4. Under the influene of air and light chloroform decomposes into

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  5. When iofoform is heated with silver poweder, the gaseous product form...

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  6. The reaction involving the treatment of benzene diazonium chloride wit...

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  7. C(6)H(5)Cl underset("625 K 300 atm")overset(NaOH(aq.))(rarr)... The pr...

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  8. (CH(3))(2)CHI overset(KOH)underset(EtOH)rarr A overset(SO(2)Cl(2))unde...

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  9. In given sequence of reaction predict X X overset(KOH)underset(H(2)O...

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  10. Iodofrom can be prepared from:

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  11. When bromoethane is treated with potassium sulphide, the main product ...

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  12. (CH(3))(2)"CHCl + Nal" rarr (CH(3))(2)"CHl+ NaCl" The above reaction...

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  13. Isopropyl alcohol is heated with a suspension of bleaching powder (CaO...

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  14. Out of monochloro, monobromo and monoiodo derivatives of ethane, the l...

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  15. Which of the following reacting substances will not liberate ethyne ga...

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  16. Which of the following on reaction with chloroform will given chloreto...

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  17. C(6)H(5)Cl overset(Ni-Al//NaOH)rarr A In this reaction A is :

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  18. The sample of chloroform used as anaesthetic is tested by:

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  19. Which of the following is not an example of Sandmeryer's reaction?

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  20. In order to prepare fluorobenzene from benzene diazonium chloride whic...

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