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(CH(3))(2)CHI overset(KOH)underset(EtOH)...

`(CH_(3))_(2)CHI overset(KOH)underset(EtOH)rarr A overset(SO_(2)Cl_(2))underset(475 K)rarr B`
The compound B in the sequence is

A

Dimethyl sulphate

B

`1,2--` Dichloro ethane

C

`3-` Chloro propene

D

`1-` Chloro`-2-` iosopropane

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The correct Answer is:
To solve the given question, we will break down the reaction sequence step by step. ### Step 1: Identify the Starting Compound The starting compound is (CH₃)₂CHI, which is 2-iodopropane. This compound has three carbon atoms and is a secondary alkyl halide. ### Step 2: Reaction with KOH in Ethanol When 2-iodopropane reacts with alcoholic KOH (KOH in ethanol), it undergoes an elimination reaction (dehydrohalogenation). In this reaction, the iodine atom (I) and a hydrogen atom (H) from the adjacent carbon are removed, leading to the formation of an alkene. - **Elimination Reaction**: - The H atom is removed from the carbon adjacent to the carbon bearing the iodine. - The I atom is removed from the carbon that has it. This results in the formation of propene (C₃H₆), which has the structure: \[ \text{CH}_2=CH-CH_3 \] ### Step 3: Identify the Product A The product formed from the first reaction is propene (C₃H₆). We will denote this compound as A. ### Step 4: Reaction with SO₂Cl₂ Next, propene (A) reacts with sulfur dichloride (SO₂Cl₂) at elevated temperature (475 K). This reaction involves the halogenation of the allylic carbon, which is the carbon adjacent to the double bond. - **Halogenation**: - The chlorine atom from SO₂Cl₂ will add to the allylic carbon (the carbon adjacent to the double-bonded carbon). In propene, the allylic carbon is the one next to the double bond. Therefore, the chlorine will substitute for a hydrogen atom on this carbon. ### Step 5: Identify the Product B The final product formed from the reaction of propene with SO₂Cl₂ is 3-chloropropene. The structure of 3-chloropropene is: \[ \text{CH}_2=CH-CH_2Cl \] ### Conclusion Thus, the compound B in the sequence is **3-chloropropene**. ### Summary of Steps: 1. Identify the starting compound (2-iodopropane). 2. React with alcoholic KOH to form propene (A). 3. React propene with SO₂Cl₂ to form 3-chloropropene (B).

To solve the given question, we will break down the reaction sequence step by step. ### Step 1: Identify the Starting Compound The starting compound is (CH₃)₂CHI, which is 2-iodopropane. This compound has three carbon atoms and is a secondary alkyl halide. ### Step 2: Reaction with KOH in Ethanol When 2-iodopropane reacts with alcoholic KOH (KOH in ethanol), it undergoes an elimination reaction (dehydrohalogenation). In this reaction, the iodine atom (I) and a hydrogen atom (H) from the adjacent carbon are removed, leading to the formation of an alkene. ...
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