Home
Class 12
CHEMISTRY
In given sequence of reaction predict X ...

In given sequence of reaction predict X
`X overset(KOH)underset(H_(2)O)rarr Y overset(Al_(2)O_(3))underset(633 K)rarr Z overset([O])rarr2` moles of `CH_(3)COOH`

A

`CH_(3) CH_(2) CH (I) CH_(3)`

B

`CH_(3)CH_(2)CH_(2)CH_(2)I`

C

`CH_(3)CH(I) CH (I) CH_(3)`

D

`CH_(3)CH(I) CH_(2) CH_(2)I`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we need to analyze the reactions and determine the structure of compound X that leads to the formation of 2 moles of acetic acid (CH₃COOH) after the series of reactions. ### Step 1: Identify the starting compound X The first reaction involves X reacting with KOH in an aqueous medium. Since KOH is a strong base and is used in an aqueous solution, it suggests that X is likely an alkyl halide. When alkyl halides react with KOH (aq), they typically undergo hydrolysis to form alcohols. **Hint:** Alkyl halides react with aqueous KOH to form alcohols. ### Step 2: Determine the product Y From the reaction of X with KOH, we get Y, which is an alcohol. The structure of Y will depend on the structure of X. Since we are looking for a compound that eventually leads to the formation of 2 moles of acetic acid, we need to consider the possible structures of Y. **Hint:** The structure of Y is derived from X by replacing the halogen with an -OH group. ### Step 3: Identify the reaction of Y with Al₂O₃ Next, Y reacts with Al₂O₃ at 633 K. Al₂O₃ is a dehydrating agent, which means it will remove water from Y to form an alkene Z. The dehydration of alcohols typically results in the formation of alkenes. **Hint:** Dehydration of alcohols using a dehydrating agent like Al₂O₃ leads to the formation of alkenes. ### Step 4: Determine the structure of Z We need to find an alkene Z that, upon oxidation, produces 2 moles of acetic acid. The oxidation of alkenes can lead to cleavage of the double bond, resulting in carboxylic acids. The alkene that can produce 2 moles of acetic acid upon oxidation is 2-butene (CH₃-CH=CH-CH₃). When oxidized, it can yield 2 moles of acetic acid. **Hint:** The alkene Z must be capable of yielding 2 moles of acetic acid upon oxidation. ### Step 5: Determine the structure of Y from Z If Z is 2-butene, we can deduce the structure of Y (the alcohol) that would dehydrate to form this alkene. The alcohol corresponding to 2-butene would be 2-butanol (CH₃-CH(OH)-CH₂-CH₃). **Hint:** The alcohol Y is formed by adding an -OH group to the alkene Z. ### Step 6: Determine the structure of X from Y Finally, to find X, we need to convert 2-butanol back into an alkyl halide. This can be done by replacing the -OH group of 2-butanol with a halogen (in this case, iodine). The resulting compound would be 2-iodobutane (CH₃-CH(I)-CH₂-CH₃). **Hint:** The alkyl halide X is formed by replacing the -OH group in Y with a halogen. ### Conclusion Thus, the compound X that leads to the formation of 2 moles of acetic acid after the series of reactions is 2-iodobutane. **Final Answer:** X = 2-iodobutane (option A).

To solve the problem step by step, we need to analyze the reactions and determine the structure of compound X that leads to the formation of 2 moles of acetic acid (CH₃COOH) after the series of reactions. ### Step 1: Identify the starting compound X The first reaction involves X reacting with KOH in an aqueous medium. Since KOH is a strong base and is used in an aqueous solution, it suggests that X is likely an alkyl halide. When alkyl halides react with KOH (aq), they typically undergo hydrolysis to form alcohols. **Hint:** Alkyl halides react with aqueous KOH to form alcohols. ### Step 2: Determine the product Y ...
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning Type|1 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning|11 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct Answer Type|28 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

In the following sequence of reaction, the product C is CH_(3)-Br overset(KCN) rarr A overset(H_(2)O^(+))rarr B overset(LiAlH_(4))underset("Ether")rarr C

In the sequence of reactions C_(6)H_(5)Broverset(Mg)underset("ether")rarr (X) overset((i)CO_(2))underset((iii)H_(3)O^(+))rarr(Y) the product (Y) is

Identify 'Z' in the following reaction series, CH_(3)CH_(2)CH_(2)Broverset(NaOH(aq))rarr(X)overset(Al_(2)O_(3))underset(heat)rarr (Y) overset(Cl_(2) //H_(2)O)rarr(Z)

CH_3COOH overset(Br_2//P) rarr (Y) overset((i) KCN) underset((ii) H_3 O^+)rarr (X) Here, (X) is :

Consider the following sequence of reactions underset((C_(4)H_(8)O_(3)))(A overset(CrO_(3))rarr B) overset("Warm")rarr CH_(3)overset(O) overset(||)C CH_(3)+CO_(2) The compound (A) is :

Consider the following sequence of reactions overset(H^(+)//Delta)rarr (X)overset(1.0_(3))underset(2.Zn//CH_(3)COOH)rarr (Y) overset(NaOH)underset(Delta)rarr The intermediate products (X) and (Y) are respectively

Which of the statements are correct about the reaction ? (A) overset(H^(o+))underset(Delta)rarr (B) overset(H_(2)O^(o+))rarr (C ) overset(Delta)rarr (D)

Reactant overset(H_(3)O^(+))rarr CH_(3)COOH+HCl

The product obtained in the reaction underset(OH)underset(|)RCH-CH_(2)overset(O)overset(||)C-OHoverset(Delta)rarr ? Is :

Complete the following reactions: overset (Benzen e) underset ((A)) overset (Ac_(2)O) underset (+AICI_(3)) rarr (B) overset ((i) MeMgBr) underset ((ii) H_(3)O^((+))) rarr (C) overset (Conc.) underset (H_(2)SO_(4)) (D) overset (1. BH_(3)//THF) underset (2. H_(2)O_(2)//O^((-))H) rarr (E)

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. C(6)H(5)Cl underset("625 K 300 atm")overset(NaOH(aq.))(rarr)... The pr...

    Text Solution

    |

  2. (CH(3))(2)CHI overset(KOH)underset(EtOH)rarr A overset(SO(2)Cl(2))unde...

    Text Solution

    |

  3. In given sequence of reaction predict X X overset(KOH)underset(H(2)O...

    Text Solution

    |

  4. Iodofrom can be prepared from:

    Text Solution

    |

  5. When bromoethane is treated with potassium sulphide, the main product ...

    Text Solution

    |

  6. (CH(3))(2)"CHCl + Nal" rarr (CH(3))(2)"CHl+ NaCl" The above reaction...

    Text Solution

    |

  7. Isopropyl alcohol is heated with a suspension of bleaching powder (CaO...

    Text Solution

    |

  8. Out of monochloro, monobromo and monoiodo derivatives of ethane, the l...

    Text Solution

    |

  9. Which of the following reacting substances will not liberate ethyne ga...

    Text Solution

    |

  10. Which of the following on reaction with chloroform will given chloreto...

    Text Solution

    |

  11. C(6)H(5)Cl overset(Ni-Al//NaOH)rarr A In this reaction A is :

    Text Solution

    |

  12. The sample of chloroform used as anaesthetic is tested by:

    Text Solution

    |

  13. Which of the following is not an example of Sandmeryer's reaction?

    Text Solution

    |

  14. In order to prepare fluorobenzene from benzene diazonium chloride whic...

    Text Solution

    |

  15. Ulimann reaction involes the use of the follwing reacants?

    Text Solution

    |

  16. The yield of chlorobenzene obtained by reaction of phenols with PCl(5)...

    Text Solution

    |

  17. Identify C in the following series C(3) H(7)Iunderset(Alc)overset(KOH)...

    Text Solution

    |

  18. Which of the following haldies has the least dipole moment?

    Text Solution

    |

  19. The chemical reaction : (CH(3))(3)CBr overset(KOH(alc.))underset(-H(...

    Text Solution

    |

  20. An ethereal solution of 4-Nitrochlorobenzene is treated with metallic ...

    Text Solution

    |