Home
Class 12
CHEMISTRY
Identify C in the following series C(3) ...

Identify C in the following series `C_(3) H_(7)Iunderset(Alc)overset(KOH)toAunderset(Delta)overset(NBS)toBunderset(Alc)overset(KCN)toC.`

A

`(CH_(3))_(2) CH-CN`

B

`CH_(2) = CH - CH_(2) CN`

C

`Br-CH=CH-CN`

D

`CH_(2) = CH - underset(Br)underset(|)(C)HCN`

Text Solution

AI Generated Solution

The correct Answer is:
To identify compound C in the given reaction series, we will analyze each step in the reaction sequence. ### Step 1: Identify the starting compound The starting compound is **iodopropane (C₃H₇I)**. The structure can be represented as: ``` CH3 | CH | CH2I ``` ### Step 2: Reaction with alcoholic KOH When iodopropane reacts with alcoholic KOH, an elimination reaction occurs. The KOH removes the iodine and a hydrogen atom, leading to the formation of a double bond. This results in the formation of **propene (C₃H₆)**: ``` CH3 | CH | CH2 ``` The byproduct of this reaction is HI. ### Step 3: Reaction with N-bromosuccinimide (NBS) Next, propene undergoes bromination at the allylic position when treated with N-bromosuccinimide (NBS). The allylic carbon is the one adjacent to the double bond. The bromine radical will add to the allylic carbon, resulting in the formation of **allyl bromide (C₃H₅Br)**: ``` CH2Br | CH | CH2 ``` The byproduct of this reaction is succinimide. ### Step 4: Reaction with alcoholic KCN Finally, the allyl bromide reacts with alcoholic KCN. The cyanide ion (CN⁻) acts as a nucleophile and replaces the bromine atom. This results in the formation of **allyl cyanide (C₃H₅CN)**: ``` CH2CN | CH | CH2 ``` The byproduct of this reaction is KBr. ### Conclusion The final compound C formed after the series of reactions is **allyl cyanide (C₃H₅CN)**. ### Answer C = Allyl cyanide (C₃H₅CN) ---

To identify compound C in the given reaction series, we will analyze each step in the reaction sequence. ### Step 1: Identify the starting compound The starting compound is **iodopropane (C₃H₇I)**. The structure can be represented as: ``` CH3 | CH ...
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning Type|1 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning|11 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct Answer Type|28 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

CH_(3)CH_(2)COOHCl_(2)overset("RedP")(to)Aunderset(Delta)overset(NaOH//CaO)(to)Bunderset(Delta)overset(Alc.KOH)(to)C 'C' is

Identify Z in the following reaction sequence C_(2)H_(5)Ioverset(alc.KOH)toXoverset(Br_(2))toYoverset(KCN)toZ

Identify the major product in the following reactions : C_(6)H_(5)-CH_(2)-underset(Br)underset( |)overset(H)overset(|)C-CH_(3) underset(Delta)overset(Alc.KOH)to ? overset(HBr)to ?

Identify (Z) in the following reaction series, C_2H_5Ioverset("Alcoholic")underset("KOH")rarr(X)overset(Br_2)rarr (Y)overset(KCN)rarr (Z)

Give the structures of A, B and C in the following: CH_(3)CHOunderset(H_(2)SO_(4))overset(K_(2)Cr_(2)O_(7))toAoverset(PCl_(5))toBunderset(AlCl_(3))overset(C_(6)H_(6))toC

Identify and name the functional groups present in the following compounds. (a) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-OH , (b) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(O)overset(||)C-OH (c ) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(O)overset(||)C-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-H , (d) H-underset(H)underset(|)overset(H)overset(|)C-underset(H)underset(|)overset(H)overset(|)C-overset(H)overset(|)C=overset(H)overset(|)C-H

CH_(3)-CH=CH_(2)underset(773 K)overset(Br_(2))to[A]underset("Heat")overset(KOH(alc.))to[B]

Give the structures of A, B and C in the following reactions: CH_3CH_2Br overset(KCN)toA overset(LiAlH_4)toB underset(0^@C)overset(HNO_2)toC

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Exercises Single Correct
  1. Ulimann reaction involes the use of the follwing reacants?

    Text Solution

    |

  2. The yield of chlorobenzene obtained by reaction of phenols with PCl(5)...

    Text Solution

    |

  3. Identify C in the following series C(3) H(7)Iunderset(Alc)overset(KOH)...

    Text Solution

    |

  4. Which of the following haldies has the least dipole moment?

    Text Solution

    |

  5. The chemical reaction : (CH(3))(3)CBr overset(KOH(alc.))underset(-H(...

    Text Solution

    |

  6. An ethereal solution of 4-Nitrochlorobenzene is treated with metallic ...

    Text Solution

    |

  7. Ethanol overset(P(4)//I(2))rarr X overset((i)KOH(alc))underset((ii) HB...

    Text Solution

    |

  8. Which of the folliwng haldies can yield ethane and also methane in a s...

    Text Solution

    |

  9. An alkyl halide with molecular formula, C(6)H(13)Br on treatment with...

    Text Solution

    |

  10. Which of the following is called Westron ?

    Text Solution

    |

  11. Which of the following represents Freen?

    Text Solution

    |

  12. Which of the following represents. Westrosol?

    Text Solution

    |

  13. The formation of an optically active compound from a chiral molecule...

    Text Solution

    |

  14. Which of the following reagents will be able to disguish between all...

    Text Solution

    |

  15. Rascing's process is employed for the commerical preparation of:

    Text Solution

    |

  16. Vinyl chloride and ethyl chloride can be distingushed by

    Text Solution

    |

  17. The disillation of bleaching powder and acetone gives:

    Text Solution

    |

  18. Chlorination of methane proceeds by

    Text Solution

    |

  19. Aryl halides are less reactive towards nucleophilic substitution react...

    Text Solution

    |

  20. How many chiral carbon atoms are present in 2.3,4- trichloropentane?

    Text Solution

    |