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Carbylamine test is performed in alcohol...

Carbylamine test is performed in alcoholic KOH by heating a mixture of

A

Chloroform and silver powder

B

Trihalogentaded methane and a primary amine

C

An alkyl halide and a primary amine

D

An alkyl cyanide and a primary amine

Text Solution

Verified by Experts

The correct Answer is:
`b`

Carbylamine test is given by `1^(@)` amine with `CHCl_(3) + KOH`
`RNH_(2) + CHCl_(3) + KOH rarr underset("Isocyanide")(R overset(o+)(N) -= overset(o-)(C)`
It gives an offensicve smell of isovyanide.
Mehcanism proceeds via carbene.
`(:C Cl_(2))` or `(:CX_(2))` or `(:CXX^(1))`
(`XX^(1) implies` Two different halogens)
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  9. Which of following is most easily cleaved by HBr.

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  10. Which will react faster with NBS?

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  11. Which is the most effective ion in an SN^(2) displacement on methyl br...

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  15. Which of the following deactivates the aromatic nucleas?

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