Home
Class 12
CHEMISTRY
Assertion (A): SN^(2) reaction is carrie...

Assertion `(A)`: `SN^(2)` reaction is carried out in the presence of polar aprotic solvent.
Reason `(R): Polar aprotic solvents do not contain acidic hydrogen.

A

Both `(A)` and `(R)` are true and `(R0` is the correct explanation of `(A)`.

B

Both `(A)` and `(R)` are true but `(R)` is not the correct explanation of `(A)`.

C

`(A) is true but `(R)` is false.

D

`(A) is false but `(R)` is true.

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding SN2 Reactions:** - The SN2 (Substitution Nucleophilic Bimolecular) reaction is a type of nucleophilic substitution where the rate of reaction depends on the concentration of both the substrate (alkyl halide) and the nucleophile. - It is characterized as a single-step mechanism where the nucleophile attacks the carbon atom from the opposite side of the leaving group, leading to a transition state where both the nucleophile and leaving group are partially bonded to the carbon. 2. **Role of Polar Aprotic Solvents:** - Polar aprotic solvents are solvents that have a significant dipole moment but do not have acidic hydrogen atoms. Examples include dimethylformamide (DMF), acetone, and dimethyl sulfoxide (DMSO). - These solvents do not donate protons (H+) and therefore do not stabilize carbocations, making them suitable for SN2 reactions. 3. **Assertion Analysis:** - The assertion states that "SN2 reactions are carried out in the presence of polar aprotic solvents." This statement is true because polar aprotic solvents enhance the nucleophilicity of the nucleophile without stabilizing the leaving group. 4. **Reason Analysis:** - The reason states that "polar aprotic solvents do not contain acidic hydrogen." This statement is also true, as polar aprotic solvents lack hydrogen atoms that can be easily donated to form H+ ions. 5. **Linking Assertion and Reason:** - While both the assertion and reason are true, the reason does not adequately explain why SN2 reactions are favored in polar aprotic solvents. The key factor is that polar aprotic solvents enhance nucleophilicity, not just the absence of acidic hydrogen. 6. **Conclusion:** - Both the assertion and reason are correct, but the reason is not the correct explanation for the assertion. Therefore, the answer is that both A and R are correct, but R is not the correct explanation of A. **Final Answer:** Option B: Both A and R are correct, but R is not the correct explanation of A. ---

**Step-by-Step Solution:** 1. **Understanding SN2 Reactions:** - The SN2 (Substitution Nucleophilic Bimolecular) reaction is a type of nucleophilic substitution where the rate of reaction depends on the concentration of both the substrate (alkyl halide) and the nucleophile. - It is characterized as a single-step mechanism where the nucleophile attacks the carbon atom from the opposite side of the leaving group, leading to a transition state where both the nucleophile and leaving group are partially bonded to the carbon. 2. **Role of Polar Aprotic Solvents:** - Polar aprotic solvents are solvents that have a significant dipole moment but do not have acidic hydrogen atoms. Examples include dimethylformamide (DMF), acetone, and dimethyl sulfoxide (DMSO). ...
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct|21 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct Answer Type|3 Videos
  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning Type|1 Videos
  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos
  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

Assertion (A) : SN^(1) reaction is carried out in the presence of a plar protic solvent. Reason (R): A polar protic solvent increases the stability of carbocation due to solvation.

How many of the following are polar aprotic solvents?

Which is more reactive nucleophile in polar aprotic solvent ?

Assetion : Permanganate titrations is not carried out in presence of hydrochloric acid. Reason : Hydrochloric acid is oxidised to chlorine.

Assertion (A) Like bromination of benzene, bromination of phenol is also carried out in the presence of Lewis acid. Reason (R) Lewis acid polarises the bromine molecule.

Assertion: Addition of HBr to propene yields 2-bromopropane but in presence of a peroxide it yields 1-bromopropane. Reason: When reaction is carried out in the presence of a peroxide it follows free radical mechanism, 2^(@) free radical is more stable than 1^(@) free radical.

Assertion (A): H_(2)SO_(4) acts as a base in the presence of HCIO_(4) . Reason (R) : Perchloride acid is stronger acid than H_(2)SO_(4) .

Assertion : Aldol condensation is usually carried out in dilute solution of a strong base. Reason : Concentrated solution of strong base involved Cannizzaro reaction.

Assertion : Most carboxylic acids exist as dimers in the vapour phase or in aprotic solvents. Reason : Higher carboxylic acids are practically insoluble in water due to the increased hydrophobic interaction of hydrocarbon part.