Home
Class 12
CHEMISTRY
A solution of ( + )-1-chloro-1-phenyleth...

A solution of ( + )-1-chloro-1-phenylethane in toluene racemises slowly in the presence of a small amount of `SbCl_(5)` due to the formation of

A

Carbanion

B

Carbene

C

Free radical

D

Carbocation

Text Solution

Verified by Experts

The correct Answer is:
`d`
NA
Promotional Banner

Topper's Solved these Questions

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Single Correct Answer Type|3 Videos

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Mutiple Correct|5 Videos

  • AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Assertion-Resoning|11 Videos

  • APPENDIX INORGANIC VOLUME 2

    CENGAGE CHEMISTRY ENGLISH|Exercise Short Answer Type|179 Videos

  • BIOMOLECULES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|8 Videos

Similar Questions

Explore conceptually related problems

A solution of (-)-1- chloro -1- phenylethane in toluene recemises slowly in the presence of a small amount of SbCl_(5) , due to the formation of

A solution of (+)2-chloro-2-phenylethane in toluene racemises slowly in the presence of small amount of SbCl_(5) due to the formation of-

The reaction of 1-phenylpropane with limited amount of chlorine in the presence of light gives mainly .

Statement-I : Chlorination of ethyl benzene with Cl_(2) in presence of heat and light mainly yield 1-chloro-1-phenyl ethane as major product. Because Statement-II : The reaction oC Curs through intermediate formation of the radical C_(6)H_(5)CH-CH_(3) .

Assertion: -But-1-ene on reaction with HBr in the presence of a peroxide produces 1-bromobutane. Reason :-It involves the formation of a primary radical.

When compound (A) is treated with conc. H_(2)SO_(4) , a reddish brown colour gas (B) is evolved. To this solution, a solution of (C ) is added slowly from the side of the test tube, a blue ring is obtained at the junction of two layers due to formation of (D). Compound (D) has formula :

PCl_5 has trigonal pyramidal geometry with sp^3 d hybridisation in gases and liquid state but in solid state it exist as ionic compound. In presence of small amount of water, PCl_5 hydrolysis to form.

Statement-1: 3M solution of alkali metal in liquid ammonia has copper bronze colour. Statement-2: copper bronze colour is due to the formation of metal cluster.

When small amount of SnCl_(2) is added to a solution of Hg^(2+) ions, a silky white precipitate is obtained.The silky white precipitate is due to the formation of:

CENGAGE CHEMISTRY ENGLISH-AROMATIC COMPOUNDS AND ALKYL AND ARYL HALIDES -Archives Single Correct
  1. The reaction of toluene with chlorine in presence of ferric chloride g...

    Text Solution

    |

  2. In the reaction of p-chlorotoluene with KNH(2) is liquid NH(3) the maj...

    Text Solution

    |

  3. Benzylchloride (C(6)H(5)CH(2)Cl) can be prepared from toluene by chlo...

    Text Solution

    |

  4. A solution of ( + )-1-chloro-1-phenylethane in toluene racemises slowl...

    Text Solution

    |

  5. product on monobromination of this compound is

    Text Solution

    |

  6. Which of the following is soluble in water

    Text Solution

    |

  7. Phenol when treated with excess of bromine water gives a white precipi...

    Text Solution

    |

  8. Chlorobenzene can be prepared by reacting aniline with

    Text Solution

    |

  9. The reaction conditions leading to the best yield of C2H5Cl are

    Text Solution

    |

  10. n-propyl bromide on treatment with ethanolic potassium hydroxide produ...

    Text Solution

    |

  11. Phenol reacts with bromine in carbon disulphide at low temperature to ...

    Text Solution

    |

  12. Monochlorination of toluene in sunlight followed by hydrolysis with aq...

    Text Solution

    |

  13. 1- Chlorobutane on reaction with alcoholic potash gives:

    Text Solution

    |

  14. Among the following compounds , the strongest acid is:

    Text Solution

    |

  15. The order of reactivities of the following alkyl halides for an S(N^2)...

    Text Solution

    |

  16. The compound that will react most readily with NaOH to form methanol i...

    Text Solution

    |

  17. Identify the set of reagents/ reaction condition ‘X’ and ‘Y’ in the fo...

    Text Solution

    |

  18. How many structures for F are possible .

    Text Solution

    |

  19. The following compound on hydrolysis in equeous acetone will give .

    Text Solution

    |

  20. CH(3)NH(2)+CHCl(3)+KOH to nitrogen containing compound +KCl+H(2)O. Nit...

    Text Solution

    |