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If the equilibrium constant of the follo...

If the equilibrium constant of the following equilibrium `SO_(2)+1//2O_(2) Leftrightarrow SO_(3) and 2SO_(3) Leftrightarrow 2SO_(2)+O_(2)` are given by `K_1 and K_2` respectively, which of the following relations is correct?

A

`K_(2)=(1/K_(1))^2`

B

`K_(1)=(1/K_(2))^3`

C

`K_(2)=(1/K_(1))`

D

`K_2=(K_1)^2`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the two given equilibrium reactions and their corresponding equilibrium constants, \( K_1 \) and \( K_2 \). ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants:** - The first reaction is: \[ SO_2 + \frac{1}{2} O_2 \leftrightarrow SO_3 \] The equilibrium constant for this reaction is \( K_1 \). - The second reaction is: \[ 2SO_3 \leftrightarrow 2SO_2 + O_2 \] The equilibrium constant for this reaction is \( K_2 \). 2. **Reverse the First Reaction:** - When we reverse the first reaction, we get: \[ SO_3 \leftrightarrow SO_2 + \frac{1}{2} O_2 \] - The equilibrium constant for the reversed reaction is given by: \[ K' = \frac{1}{K_1} \] 3. **Adjust the Reversed Reaction:** - Now, we need to multiply the reversed reaction by 2 to match the second reaction: \[ 2SO_3 \leftrightarrow 2SO_2 + O_2 \] - When we multiply the equilibrium expression by 2, the new equilibrium constant becomes: \[ K_2 = (K')^2 = \left(\frac{1}{K_1}\right)^2 = \frac{1}{K_1^2} \] 4. **Final Relationship:** - From the above steps, we can conclude that: \[ K_2 = \frac{1}{K_1^2} \] ### Conclusion: The correct relationship between the equilibrium constants \( K_1 \) and \( K_2 \) is: \[ K_2 = \frac{1}{K_1^2} \]
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