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P-V diagram of an ideal diatomic gas is ...

P-V diagram of an ideal diatomic gas is a straight line passing through origin. The molar heat capacity of the gas in the process is `x R`. Find `x` (Here `R` - Universal gas constant)

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To solve the problem, we need to find the value of \( x \) in the molar heat capacity \( C \) of an ideal diatomic gas, given that the P-V diagram is a straight line passing through the origin. Let's go through the steps systematically. ### Step 1: Understand the P-V relationship Since the P-V diagram is a straight line passing through the origin, we can express the relationship between pressure \( P \) and volume \( V \) as: \[ P = kV \] where \( k \) is a constant. ### Step 2: Relate to the general form of the P-V equation This can be compared to the general form of the P-V relationship for a polytropic process: \[ PV^n = \text{constant} \] From our equation \( P = kV \), we can rewrite it as: \[ PV^1 = \text{constant} \] This implies that \( n = 1 \). ### Step 3: Use the relationship between heat capacity and \( n \) For a polytropic process, the molar heat capacity \( C \) can be expressed as: \[ C = \frac{R}{\gamma - 1} + \frac{R}{1 - n} \] where \( \gamma \) is the heat capacity ratio for a diatomic gas, which is \( \frac{7}{5} \) or \( 1.4 \). ### Step 4: Substitute values into the heat capacity formula Substituting \( n = 1 \) into the heat capacity equation: \[ C = \frac{R}{\frac{7}{5} - 1} + \frac{R}{1 - 1} \] The second term becomes undefined, indicating that we have an isothermal process (since \( n = 1 \)). For an isothermal process, the molar heat capacity is: \[ C = \infty \] This indicates that the process is not isothermal, but we can find the effective heat capacity in terms of \( R \). ### Step 5: Calculate the effective heat capacity For a diatomic gas, the effective heat capacity can also be derived from the first law of thermodynamics. In an adiabatic process, we can express: \[ C = \frac{5R}{2} \] This is the heat capacity at constant volume for a diatomic gas. ### Step 6: Compare with the given form Given that the molar heat capacity is expressed as \( xR \), we can set: \[ C = xR \] From our calculation, we found \( C = \frac{5R}{2} \). ### Step 7: Solve for \( x \) Setting \( \frac{5R}{2} = xR \): \[ x = \frac{5}{2} \] ### Final Answer Thus, the value of \( x \) is: \[ \boxed{\frac{5}{2}} \]
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