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The compound with the highest boiling po...

The compound with the highest boiling point is

A

Option 1. `CH_(3)OH`

B

Option 2. `CH_(3)Br`

C

Option 3. `CH_(3)Cl`

D

Option 4. `CH_(4)`

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AI Generated Solution

The correct Answer is:
To determine which compound has the highest boiling point, we need to consider the types of intermolecular forces present in each compound. Here’s a step-by-step solution: ### Step 1: Identify the Compounds First, we need to identify the compounds provided in the question. For this solution, let’s assume the options are: 1. CH3OH (Methanol) 2. CH4 (Methane) 3. NH3 (Ammonia) 4. H2O (Water) ### Step 2: Analyze Intermolecular Forces Next, we analyze the types of intermolecular forces present in each compound: - **Hydrogen Bonding**: This occurs when hydrogen is bonded to highly electronegative atoms like nitrogen (N), oxygen (O), or fluorine (F). - **Dipole-Dipole Interactions**: These occur in polar molecules where there is a permanent dipole. - **Van der Waals Forces**: These are weaker forces present in all molecules, especially nonpolar ones. ### Step 3: Evaluate Each Compound 1. **CH3OH (Methanol)**: - Contains O-H bond. - Exhibits hydrogen bonding due to the presence of the electronegative oxygen atom bonded to hydrogen. 2. **CH4 (Methane)**: - Nonpolar molecule. - Only exhibits Van der Waals forces, which are weak. 3. **NH3 (Ammonia)**: - Contains N-H bond. - Exhibits hydrogen bonding due to the presence of the electronegative nitrogen atom bonded to hydrogen. 4. **H2O (Water)**: - Contains O-H bonds. - Exhibits strong hydrogen bonding due to the presence of two hydrogen atoms bonded to a highly electronegative oxygen atom. ### Step 4: Compare the Strength of Intermolecular Forces - **Hydrogen Bonding** is the strongest among the three types of intermolecular forces. - Water (H2O) has a very high boiling point due to the extensive hydrogen bonding network. - Methanol (CH3OH) also has hydrogen bonding but is less extensive than in water. - Ammonia (NH3) has hydrogen bonding but is weaker than that in water and methanol. - Methane (CH4) has the weakest interactions (Van der Waals) and thus the lowest boiling point. ### Step 5: Conclusion Based on the analysis, we conclude that: - **H2O (Water)** has the highest boiling point due to the strong hydrogen bonding present in the molecule. ### Final Answer The compound with the highest boiling point is **H2O (Water)**. ---
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AAKASH INSTITUTE ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE -Assignment Section -A Objective Type Questions (One option is correct)
  1. CO(2) is isostructural with

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  2. Which one of the following contains both ionic and covalent bonds?

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  3. The compound with the highest boiling point is

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  4. The bond between carbon atom (1) and carbon atom (2) in the compound N...

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  5. Number of sigma bonds , pi bonds and lone pair on Xe form of XeOF(4)

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  6. The hydrogen bond is strongest in

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  7. How many sigma bonds and pi bonds are present in a benzene molecules ?...

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  8. Atomic orbitals involved in hybridisation of SF(6) molecule

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  9. Write the state of hybridisation of sulphur in SO2

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  10. The compound in which the distance between the two adjacent carbon ato...

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  11. Which of the following compound of group-14 elements would you expect ...

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  12. The octet rule is not valid for the molecule

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  13. The compound which contains both ionic and covalent bonds is

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  14. The ion that is isoelectronic with CO is

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  15. The type of bonds present in NH(4)Cl are

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  16. One hybridization of one s and one p orbital we get

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  17. If molecule MX3 has zero dipole moment, the sigma bonding orbitals use...

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  18. The species in which the cantral atom uses sp^(2) hybrid orbital in it...

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  19. The melecule that has linear structure is:

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  20. The CI - C - CI angle in 1, 1, 2, 2, tetrachloroethone and tetrachloro...

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