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Number of right angle bonds in PCl(5) is...

Number of right angle bonds in `PCl_(5)` is _______.

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To determine the number of right angle bonds in PCl₅, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the central atom and its valence electrons**: - The central atom in PCl₅ is phosphorus (P). Phosphorus has 5 valence electrons. 2. **Count the number of surrounding atoms**: - In PCl₅, there are 5 chlorine (Cl) atoms surrounding the phosphorus atom. 3. **Determine the hybridization**: - The hybridization can be calculated using the formula: \[ \text{Hybridization} = \frac{(n + m)}{2} \] where \(n\) is the number of valence electrons of the central atom and \(m\) is the number of surrounding atoms. Here, \(n = 5\) (from P) and \(m = 5\) (from 5 Cl atoms): \[ \text{Hybridization} = \frac{(5 + 5)}{2} = \frac{10}{2} = 5 \] - This corresponds to \(sp^3d\) hybridization. 4. **Visualize the molecular geometry**: - PCl₅ has a trigonal bipyramidal geometry. In this structure, there are two types of bonds: - **Axial bonds**: These are the bonds that are oriented vertically (up and down). - **Equatorial bonds**: These are the bonds that are in the horizontal plane. 5. **Identify the angles between bonds**: - The axial bonds are at 90 degrees to the equatorial bonds. - Specifically, the angle between the two axial bonds is 180 degrees, while the angle between an axial bond and an equatorial bond is 90 degrees. 6. **Count the right angle bonds**: - In the PCl₅ structure, there are 2 axial bonds that are at right angles (90 degrees) to the 3 equatorial bonds. Therefore, there are 2 right angle bonds in total. ### Final Answer: The number of right angle bonds in PCl₅ is **2**. ---
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