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In this reaction: S(2)O(8)^(2-)+2I^(-) t...

In this reaction: `S_(2)O_(8)^(2-)+2I^(-) to 2SO_(4)^(2-)+I_(2)`

A

Oxidation of iodide into iodine takes place

B

Reduction of iodine into iodide takes place

C

Both oxidation and reduction of iodine takes place

D

All of these

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The correct Answer is:
To solve the question regarding the reaction \( S_2O_8^{2-} + 2I^{-} \rightarrow 2SO_4^{2-} + I_2 \), we need to analyze the oxidation and reduction processes involved. ### Step-by-Step Solution: **Step 1: Identify the oxidation states of the elements involved.** - In the reactants, the oxidation state of iodine in \( I^{-} \) is -1. - In the products, the oxidation state of iodine in \( I_2 \) is 0. - The oxidation state of sulfur in \( S_2O_8^{2-} \) is +7, and in \( SO_4^{2-} \), it is +6. **Step 2: Determine the changes in oxidation states.** - For iodine: - The change from -1 (in \( I^{-} \)) to 0 (in \( I_2 \)) indicates that iodine is losing electrons. - This is an oxidation process. - For sulfur: - The change from +7 (in \( S_2O_8^{2-} \)) to +6 (in \( SO_4^{2-} \)) indicates that sulfur is gaining electrons. - This is a reduction process. **Step 3: Conclude the type of reactions occurring.** - Since iodine is losing electrons, it is being oxidized. - Since sulfur is gaining electrons, it is being reduced. **Step 4: Identify the correct answer.** - The question asks about the oxidation and reduction processes taking place. The correct option is that oxidation of iodine into iodine takes place. ### Final Answer: The correct option is: **Oxidation of iodine into iodine takes place.**
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Manganese ions (Mn^(2+)) can be oxidised by Persulphate ions S_(2)O_(8)^(2-) according to the following half-equations, S_(2)O_(8)^(2-)+2e^(-) to 2SO_(4)^(2-) Mn^(2+)+4H_(2)O to MnO_(4)^(-)+4H_(2)O to MnO_(4)^(-)+8H^(+)+5e^(-) How many moles of S_(2)O_(8)^(2-) are required to oxidise 1mole of Mn^(2+) ?

The experiment rate law for the reaction S_(2)O_(8)^(2-)(aq) + 2I^(ɵ)(aq) rarr 2SO_(4)^(2-) (aq) + I_(2)(aq) is k[S_(2)O_(8)^(2-)] [I^(ɵ)] . How would the rate change if (a) Concentration of S_(2)O_(8)^(2-) is halved. (b) Concentration of S_(2)O_(8)^(2-) and I^(ɵ) are halved.

The reaction S_(2)O_(8)^(2-) + 3I^(ɵ) rarr 2SO_(4)^(2-) + I_(3)^(ɵ) is of first order both with respect to persulphate and iofide ions. Taking the initial concentration as a and b , respectively, and taking x as the concentration of the triofide at time t , a differential rate equation can be written. Two suggested mechanism for the reaction are: I. S_(2)O_(8)^(2-)+I^(ɵ) hArr SO_(4)I^(ɵ)+SO_(4)^(2-) ("fast") I^(ɵ)+SO_(4)I^(ɵ) overset(k_(1))rarrI_(2) + SO_(4)^(2-) (show) I^(ɵ) + I_(2) overset(k_(2))rarr I_(3)^(ɵ) ("fast") II. S_(2)O_(8)^(2-) + I^(ɵ) overset(k_(1))rarr S_(2)O_(8) I^(2-) (slow) S_(2)O_(8)I^(3-) overset(k_(2))rarr2SO_(4)^(2-)+I^(o+) ("fast") I^(o+) + I^(ɵ) overset(k_(3)) rarr I_(2) ("fast") I_(2) + I^(o+) overset(k_(4))rarr I_(3)^(ɵ) ("fast") The general difference equation for the above reaction is

The reaction S_(2)O_(8)^(2-) + 3I^(ɵ) rarr 2SO_(4)^(2-) + I_(3)^(ɵ) is of first order both with respect to persulphate and iofide ions. Taking the initial concentration as a and b , respectively, and taking x as the concentration of the triofide at time t , a differential rate equation can be written. Two suggested mechanism for the reaction are: I. S_(2)O_(8)^(2-)+I^(ɵ) hArr SO_(4)I^(ɵ)+SO_(4)^(2-) ("fast") I^(ɵ)+SO_(4)I^(ɵ) overset(k_(1))rarrI_(2) + SO_(4)^(2-) (show) I^(ɵ) + I_(2) overset(k_(2))rarr I_(3)^(ɵ) ("fast") II. S_(2)O_(8)^(2-) + I^(ɵ) overset(k_(1))rarr S_(2)O_(8) I^(2-) (slow) S_(2)O_(8)I^(3-) overset(k_(2))rarr2SO_(4)^(2-)+I^(o+) ("fast") I^(o+) + I^(ɵ) overset(k_(3)) rarr I_(2) ("fast") I_(2) + I^(o+) overset(k_(4))rarr I_(3)^(ɵ) ("fast") For the reaction I_(2)+2S_(2)O_(3)^(2-) rarr S_(4)O_(6)^(2-) + 2I^(ɵ) I. (-d[I_(2)])/(dt) = -(1)/(2) (d[S_(2)O_(3)^(2-)])/(dt) II. (-d[I_(2)])/(dt) = -2 (d[S_(2)O_(3)^(2-)])/(dt) III. (-d[I_(2)])/(dt) = -2 (d[I^(ɵ)])/(dt) xx (d[S_(2)O_(3)^(2-)])/(dt) IV. (d[S_(4)O_(6)^(2-)])/(dt) = (1)/(2)(d[I^(ɵ)])/(dt) The correct option is

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) .

In the reaction, 2S_(2)O_(3)^(2-)+I_(2)rarrS_(4)O_(6)^(2-)+2I^(-) . The eq. wt. of Na_(2)S_(2)O_(3) is equal to its:

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

In the reaction, I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(-)+S_(4)O_(6)^(2-) . Equivalent wieght of iodine will be equal to

A solution of 0.1 M KMnO_(4) is used for the reaction S_(2)O_(3)^(2-) + 2MnO_(4)^(-) + H_(2)O to MnO_(2)+SO_(4)^(2-) + OH^(-) What volume of solution in ml will be required to react with 0.158 gm of Na_(2)S_(2)O_(3) ?

A constant current was flowen for 1 mi n through a solution of Kl . At the end of experiment, liberated I_(2) consumed 150mL of 0.01M solution of Na_(2)S_(2)O_(3) following the reaction : I_(2)+2S_(2)O_(3)^(2-) rarr 2I^(c-)+S_(4)O_(6)^(2-) What was the average rate of current flow in ampere ?

AAKASH INSTITUTE ENGLISH-REDOX REACTIONS-Assignment (Section A) (Objective type Questions (one option is correct))
  1. The oxidation number of S in S(8),S(2)F(2), and H(2)S, respectively, a...

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  2. The oxidation number of C in HNC is

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  3. The oxidation number of Cl in CaOCl(2) is

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  4. Which of the following molecules can act as an oxidising agent as well...

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  5. The oxidation state of iodine in ICI(3) is

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  6. The pair of compounds having metals in their highest oxidation state i...

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  7. Consider a titration of potassium dichromate solution with acidified M...

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  8. Number of moles of MnO(4)^(-) required to oxidise one mole of ferrous ...

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  9. The reaction,P(4)+3NaOH+3H(2)O to 3NaH(2)PO(2)+PH(3) is an example of

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  10. CrO(5) has structure as shown The oxidation number of chromium in...

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  11. The oxidation states of S atom in S(4)O(6)O^(2-) from left to right re...

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  12. The oxidation number of phosphorus in PO(4)^(3-), P(4)O(10), and P(2)O...

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  13. The reaction 5H(2)O(2)+XClO(2)+2OH^(-) rarr XCl^(-)+YO(2)+6H(2)O i...

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  14. Nitrogen forms a variety of compounds in all oxidation states ranging ...

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  15. KMnO(4) is a strong oxidising agent in acidic medium. To provide acidi...

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  16. Oxidation states of P in H(4)P(2)O(5),H(4)P(2)O(6),H(4)P(2)O(7) respec...

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  17. In this reaction: S(2)O(8)^(2-)+2I^(-) to 2SO(4)^(2-)+I(2)

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  18. Which of the following has the highest value of E("red")^(@) ?

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  19. Which of the following species has an atom with +6 oxidation state?

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  20. The oxidant which cannot act as a reducing agent is

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