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Concrete is produced form a mixture of c...

Concrete is produced form a mixture of cement, water and small stones. Small amount of gypsum, `CaSO_(4).2H_(2)O` is added in cement production to improve the subsequent hardening of concrete. The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate `CaSO_(4)(1)/(2)H_(2)O` according to reaction.
`CaSO_(4)2H_(2)O(s) rarr CaSO_(4)(1)/(2)H_(2)O(s)+(3)/(2)H_(2)O(g)`
The `Delta_(f)H^(Theta) of CaSO_(2).2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s),H_(2)O(g)`
are `-2021.0 kJ mol^(-1), -1575.0 kJ mol^(-1)` and `-241.8 kJ mol^(-1)`, respectively. The respective values of their standard entropies are `194.0, 130.0` and `188.0 J K^(-1)mol^(-1)`. The values of `R = 8.314JK^(-1)mol^(-1) = 0.0831L` bar `mol^(-1)K^(-1)`.
Answer the following questions on the basis of above information.
Heat change occurring during conversion of `1kg` of `CaSO_(4).2H_(2)O(s)` (molar mass `172g mol^(-1))` of `CaSO_(4)(1)/(2)H_(2)O(s)` is equal to

A

Oxidising agent

B

Reducing agent

C

Oxidising as well as reducing agent

D

Catalyst

Text Solution

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The correct Answer is:
A
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Concrete is produced form a mixture of cement, water and small stones. Small amount of gypsum, CaSO_(4).2H_(2)O is added in coment production to impove the subsequent hardening of concrete. The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate CaSO_(4)(1)/(2)H_(2)O according to reaction. CaSO_(4)2H_(2)O(s) rarr CaSO_(4)(1)/(2)H_(2)O(s)+(3)/(2)H_(2)O(g) The Delta_(f)H^(Theta) of CaSO_(2).2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s),H_(2)O(g) are -2021.0 kJ mol^(-1), -1575.0 kJ mol^(-1) and -241.8 kJ mol^(-1) , respectively. The respective values of their standard entropies are 194.0, 130.0 and 188.0 J K^(-1)mol^(-1) . The values of R = 8.314JK^(-1)mol^(-1) = 0.0831L bar mol^(-1)K^(-1) . Answer the following questions on the basis of above information. The formation of CaSO_(4)(1)/(2)H_(2)O at 298K is

Concrete is produced form a mixture of cement, water and small stones. Small amount of gypsum, CaSO_(4).2H_(2)O is added in coment production to impove the subsequent hardening of concrete. The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate CaSO_(4)(1)/(2)H_(2)O according to reaction. CaSO_(4)2H_(2)O(s) rarr CaSO_(4)(1)/(2)H_(2)O(s)+(3)/(2)H_(2)O(g) The Delta_(f)H^(Theta) of CaSO_(2).2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s),H_(2)O(g) are -2021.0 kJ mol^(-1), -1575.0 kJ mol^(-1) and -241.8 kJ mol^(-1) , respectively. The respective values of their standard entropies are 194.0, 130.0 and 188.0 J K^(-1)mol^(-1) . The values of R = 8.314JK^(-1)mol^(-1) = 0.0831L bar mol^(-1)K^(-1) . Answer the following questions on the basis of above information. The value of DeltaG^(Theta) for the reaction at 298K is

Concrete is produced form a mixture of cement, water and small stones. Small amount of gypsum, CaSO_(4).2H_(2)O is added in coment production to impove the subsequent hardening of concrete. The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate CaSO_(4)(1)/(2)H_(2)O according to reaction. CaSO_(4)2H_(2)O(s) rarr CaSO_(4)(1)/(2)H_(2)O(s)+(3)/(2)H_(2)O(g) The Delta_(f)H^(Theta) of CaSO_(2).2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s),H_(2)O(g) are -2021.0 kJ mol^(-1), -1575.0 kJ mol^(-1) and -241.8 kJ mol^(-1) , respectively. The respective values of their standard entropies are 194.0, 130.0 and 188.0 J K^(-1)mol^(-1) at 298K. The values of R = 8.314JK^(-1)mol^(-1) = 0.0831L bar mol^(-1)K^(-1) . Answer the following questions on the basis of above information. The value of equilibrium for reaction is

Concrete is produced form a mixture of cement, water and small stones. Small amount of gypsum, CaSO_(4).2H_(2)O is added in coment production to impove the subsequent hardening of concrete. The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate CaSO_(4)(1)/(2)H_(2)O according to reaction. CaSO_(4)2H_(2)O(s) rarr CaSO_(4)(1)/(2)H_(2)O(s)+(3)/(2)H_(2)O(g) The Delta_(f)H^(Theta) of CaSO_(2).2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s),H_(2)O(g) are -2021.0 kJ mol^(-1), -1575.0 kJ mol^(-1) and -241.8 kJ mol^(-1) , respectively. The respective values of their standard entropies are 194.0, 130.0 and 188.0 J K^(-1)mol^(-1) . The values of R = 8.314JK^(-1)mol^(-1) = 0.0831L bar mol^(-1)K^(-1) . Answer the following questions on the basis of above information. The equilibrium pressure of water vapour in closed vessel containing CaSO_(4)2H_(2)O(s),CaSO_(4)(1)/(2)H_(2)O(s) and H_(2)O(g) at 298K (Antilog -3.14 = 7.24 xx 10^(-4)) is

CaSO_(3)darr+H_(2)SO_(4)toCaSO_(4)+SO_(2)uarr+H_(2)O

CaSO_(3)darr+H_(2)SO_(4)toCaSO_(4)+SO_(2)uarr+H_(2)O

In the reaction. H_(2)S+H_(2)O_(2) rarr S+2H_(2)O describes

The equilibrium constant for the reaction CaSO_(4).H_(2)O(s)hArr CaSO_(4).3H_(2)O(s)+2H_(2)O(g) is equal to

Ca(OH)_(2)+SO_(2) to CaSO_(3)darr+H_(2)O

Ca(OH)_(2)+SO_(2) to CaSO_(3)darr+H_(2)O

AAKASH INSTITUTE ENGLISH-REDOX REACTIONS-Assignment (Section B) (Objective type Questions (one option is correct))
  1. which of the following is a redox reaction ?

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  2. Concrete is produced form a mixture of cement, water and small stones....

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  3. Which can act as an oxidising as well as a reducing agent ?

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  4. The number of electrons required to balance the following equation are...

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  5. Which of the following statement is correct about oxidation number ?

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  6. Which can act as a reducing agent ?

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  7. The oxidation number of Fe in Fe(0.94)O is

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  8. In this reaction 4Al + 3O(2) to 4Al^(3+) + 6O^(2-) which of the follow...

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  9. Calculate the oxidation numbers of Cr in K(3)CrO(8):

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  10. Peroxides are basic in nature and they form hydrogen peroxides on trea...

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  11. What is the difference in oxidation state of nitrogen in between hydro...

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  12. In which one of the following changes there are transfer of five elect...

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  13. How many gm of K(2)Cr(2)O(7) is present in 1 L of its N/10 solution in...

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  14. When Cu(2)S is converted into Cu^(2+) & SO(2) then equivalent weight o...

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  15. Which of the following changes involve reduction ?

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  16. FeS to Fe^(3+) + SO(3) Eq. wt. of FeS for this change is (mol. Wt....

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  17. The reaction Cl(2) + S(2)O(3)^(2-) + OH^(-) to SO(4)^(2-) + Cl^(-)...

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  18. The number of moles of KMnO4 that are needed to react completely with ...

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  19. 200 ml of 0.01 M KMnO(4) oxidise 20 ml of H(2)O(2) sample in acidic me...

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  20. If equal volumes of 1 M KMnO(4) and 1M K(2)Cr(2)O(7) solutions are all...

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